Influence of the Support on Activity and Stability of Ni and Ni-Mo Catalysts in the Hydroprocessing of Fatty Acids into Motor Fuels Components Научная публикация
| Журнал |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Вых. Данные | Год: 2022, Том: 644, Номер статьи : 118801, Страниц : 11 DOI: 10.1016/j.apcata.2022.118801 | ||
| Ключевые слова | Undiluted fatty acid, One-pot process, Hydrodeoxygenation, Zeolite, Nickel | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0005 |
Реферат:
Ni/zeolite catalyst, as well as a series of modified molybdenum MoNi/zeolite catalysts (zeolite = ZSM-5, ZSM-23, MOR, Y) were investigated in the hydroprocessing of an undiluted fatty acid mixture in a batch reactor at a temperature of 350 °C and an initial hydrogen pressure of 60 bar. The highest conversion (70 %) of the fatty acid mixture was achieved over ZSM-5 supported catalytic system in 7 h. The fresh and spent catalytic systems were characterized by XRD, TEM, TPR-H2, TPD-NH3, CHNS. Influence of the support, and the modifier, on the catalytic activity, stability under reaction conditions, and selectivity to iso-alkanes were shown. Leaching of the active component from the surface of all catalysts was found. The largest amount of residual nickel was observed in catalysts based on ZSM-5 zeolite - ca.57 % of the initial metal content. Modification with molybdenum did not improve the stability of catalysts to metal leaching.
Библиографическая ссылка:
Shinkevich K.S.
, Kukushkin R.G.
, Bulavchenko O.A.
, Zaikina O.O.
, Alekseeva M.V.
, Ruvinskiy P.S.
, Yakovlev V.A.
Influence of the Support on Activity and Stability of Ni and Ni-Mo Catalysts in the Hydroprocessing of Fatty Acids into Motor Fuels Components
Applied Catalysis A: General. 2022. V.644. 118801 :1-11. DOI: 10.1016/j.apcata.2022.118801 WOS Scopus РИНЦ CAPlus OpenAlex
Influence of the Support on Activity and Stability of Ni and Ni-Mo Catalysts in the Hydroprocessing of Fatty Acids into Motor Fuels Components
Applied Catalysis A: General. 2022. V.644. 118801 :1-11. DOI: 10.1016/j.apcata.2022.118801 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 26 апр. 2022 г. |
| Принята к публикации: | 26 июл. 2022 г. |
| Опубликована online: | 28 июл. 2022 г. |
| Опубликована в печати: | 25 авг. 2022 г. |
Идентификаторы БД:
| Web of science: | WOS:000863090500007 |
| Scopus: | 2-s2.0-85135685723 |
| РИНЦ: | 53756117 |
| Chemical Abstracts: | 2022:2100303 |
| OpenAlex: | W4288075244 |