Single-Atom Pd Catalysts Supported on Covalent Triazine Frameworks for Hydrogen Production from Formic Acid | Sciact - CRIS-system of Boreskov Institute of Catalysis

Single-Atom Pd Catalysts Supported on Covalent Triazine Frameworks for Hydrogen Production from Formic Acid Full article

Journal

ACS Applied Nano Materials
ISSN: 2574-0970

Output data

Year: 2022, Volume: 5, Number: 9, Pages: 12887–12896 Pages count : 10 DOI: 10.1021/acsanm.2c02746

Tags

single-atom catalyst; Pd; formic acid decomposition; hydrogen production; covalent triazine frameworks

Authors

Bulushev Dmitri A. ¹ , Golub Fedor S. ¹ , Trubina Svetlana V. ² , Zvereva Valentina V. ² , Bulusheva Lyubov G. ² , Gerasimov Evgeny Y. ¹ , Navlani-García Miriam ³ , Krot Anna D. ⁴ , Jena Himanshu Sekhar ⁵

Affiliations

1	Department of Nontraditional Catalytic Processes, Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia
2	Laboratory of Physical Chemistry of Condensed Matter, Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia
3	Department of Inorganic Chemistry, University of Alicante, E-03080 Alicante, Spain
4	Lomonosov Moscow State University, 119991 Moscow, Russia
5	Department of Chemistry, University of Ghent, 9000 Ghent, Belgium

Funding (2)

1	Russian Science Foundation	22-23-00608
2	Ghent University	GOA010-17

According to our knowledge, single-atom Pd catalysts supported on covalent triazine frameworks (CTF) have not been studied in the production of hydrogen from formic acid. Therefore, we synthesized 1 wt % Pd single-atom catalysts based on CTF-1, pyCTF, and bipyCTF supports and tested them in the gas-phase decomposition of formic acid. The results were compared with those obtained for a Pd catalyst supported on mesoporous graphitic-type carbon (Pd/C) with nanoparticles (∼2.3 nm). The catalysts were characterized by high-angle annular dark-field/scanning transmission electron microscopy (HAADF/STEM), extended X-ray absorption fine structure/X-ray absorption near-edge structure (EXAFS/XANES), and X-ray photoelectron spectroscopy (XPS) methods. The following order of catalytic activity was obtained: Pd/CTF-1 > Pd/C > Pd/pyCTF ≥ Pd/bipyCTF. The best performance of the Pd/CTF-1 catalyst was associated with Pd2+–C2N2 sites. Pd2+–N4 sites formed on pyCTF and bipyCTF supports showed lower catalytic activity. The selectivity trend at temperatures above 500 K was as follows: Pd/bipyCTF > Pd/pyCTF > Pd/CTF-1 > Pd/C. For the Pd/bipyCTF catalyst, the selectivity reached 99.8%, which is very high for this temperature range. These results may be important for the development of CTF-based catalysts for hydrogen production reactions.

Bulushev D.A. , Golub F.S. , Trubina S.V. , Zvereva V.V. , Bulusheva L.G. , Gerasimov E.Y. , Navlani-García M. , Krot A.D. , Jena H.S.
Single-Atom Pd Catalysts Supported on Covalent Triazine Frameworks for Hydrogen Production from Formic Acid
ACS Applied Nano Materials. 2022. V.5. N9. P.12887–12896. DOI: 10.1021/acsanm.2c02746 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jun 24, 2022
Accepted:	Aug 12, 2022
Published online:	Aug 22, 2022
Published print:	Sep 23, 2022

Web of science:	WOS:000848501400001
Scopus:	2-s2.0-85137278787
Elibrary:	53768806
Chemical Abstracts:	2022:2161930
Chemical Abstracts (print):	180:367349
OpenAlex:	W4292573457

DB	Citing
Web of science	23
Scopus	23
Elibrary	17
OpenAlex	24