One-Pot Synthesis of Menthol Starting from Citral over Ni Supported on Attapulgite-H-Beta-38 Extrudates in a Continuous Flow: Effect of Metal Location Full article
| Journal |
Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045 |
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| Output data | Year: 2022, Volume: 61, Number: 35, Pages: 12998–13010 Pages count : 13 DOI: 10.1021/acs.iecr.2c02345 | ||||||
| Tags | Catalysts, Diffraction, Metals, Nickel, Particle size | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0008 |
| 2 | Academy of Finland |
Abstract:
The one-pot synthesis of menthol from citral in a continuous mode was investigated over three different types of extrudates, namely Ni supported on H-Beta-38 and extruded with attapulgite, Ni supported on attapulgite and extruded with H-Beta-38, and the extrudates, which were shaped after deposition of Ni on both H-Beta-38 and attapulgite in the powder form. These composite catalysts were characterized by X-ray diffraction, transmission and scanning electron microscopy, temperature-programmed reduction of H2, mechanical strength, and pyridine adsorption desorption. These three types of extrudates exhibited different metal particle sizes and acidity. The most promising catalyst in the one-pot menthol synthesis was Ni supported first on H-Beta-38 and then extruded with attapulgite giving a 45% yield of menthols in a trickle bed reactor. This catalyst exhibited 10 nm nickel particles and a rather high amount of strong Brønsted acid sites.
Cite:
Simakova I.L.
, Mäki-Arvela P.
, Martínez-Klimov M.
, Muller J.
, Vajglová Z.
, Peurla M.
, Eränen K.
, Murzin D.Y.
One-Pot Synthesis of Menthol Starting from Citral over Ni Supported on Attapulgite-H-Beta-38 Extrudates in a Continuous Flow: Effect of Metal Location
Industrial and Engineering Chemistry Research. 2022. V.61. N35. P.12998–13010. DOI: 10.1021/acs.iecr.2c02345 WOS Scopus РИНЦ ANCAN OpenAlex
One-Pot Synthesis of Menthol Starting from Citral over Ni Supported on Attapulgite-H-Beta-38 Extrudates in a Continuous Flow: Effect of Metal Location
Industrial and Engineering Chemistry Research. 2022. V.61. N35. P.12998–13010. DOI: 10.1021/acs.iecr.2c02345 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jun 30, 2022 |
| Accepted: | Aug 14, 2022 |
| Published online: | Aug 25, 2022 |
| Published print: | Sep 7, 2022 |
Identifiers:
| Web of science: | WOS:000848752900001 |
| Scopus: | 2-s2.0-85137303752 |
| Elibrary: | 50741550 |
| Chemical Abstracts: | 2022:2213057 |
| Chemical Abstracts (print): | 181:149208 |
| OpenAlex: | W4293243649 |