Selective Hydrogenation of 5-Acetoxymethylfurfural over Cu-Based Catalysts in a Flow Reactor: Effect of Cu-Al Layered Double Hydroxides Synthesis Conditions on Catalytic Properties Full article
| Journal |
Catalysts
ISSN: 2073-4344 |
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| Output data | Year: 2022, Volume: 12, Number: 8, Article number : 878, Pages count : 14 DOI: 10.3390/catal12080878 | ||
| Tags | Cu-based catalysts; layered double hydroxides; catalyst preparation; selective hydrogenation; 5-Acetoxymethylfurfural; flow reactor; heterogeneous catalysis | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0008 |
Abstract:
Cu-containing layered double hydroxides (LDHs) were synthesized by a co-precipitation method at different reaction conditions, such as aging time, pH, precipitation rate and synthesis temperature. The effect of these parameters on the structure and chemical composition of the catalysts were investigated using a set of physical methods, including thermogravimetric analysis (TGA), X-ray diffraction (XRD), H-2-TPR and in situ X-ray photoelectron spectroscopy (XPS). It allowed for checking of the reducibility of the samples. 5-Acetoxymethylfurfural was catalytically hydrogenated to 5-(acetoxymethyl)-2-furanmethanol (AMFM) over Cu-containing catalysts synthesized from layered double hydroxides so as to investigate its catalytic properties in flow reaction. It was shown that synthesis pH decreasing from 10 to 8 resulted in rise of AMF conversion that coincided with the higher surface Cu/Al ratio obtained by XPS. Preferable aging time of LDH materials for obtaining the most active catalyst was 2 h, an amount of time that favored the production of the catalyst with high surface Cu/Al ratio up to 0.38. Under optimized reaction conditions, the AMFM yield was 98%. Finally, a synthesis strategy for the preparation of highly efficient Cu-based hydrogenation catalyst with optimized characteristics is suggested.
Cite:
Bukhtiyarova M.V.
, Bulavchenko O.A.
, Bukhtiyarov A.V.
, Nuzhdin A.L.
, Bukhtiyarova G.A.
Selective Hydrogenation of 5-Acetoxymethylfurfural over Cu-Based Catalysts in a Flow Reactor: Effect of Cu-Al Layered Double Hydroxides Synthesis Conditions on Catalytic Properties
Catalysts. 2022. V.12. N8. 878 :1-14. DOI: 10.3390/catal12080878 WOS Scopus РИНЦ AN OpenAlex
Selective Hydrogenation of 5-Acetoxymethylfurfural over Cu-Based Catalysts in a Flow Reactor: Effect of Cu-Al Layered Double Hydroxides Synthesis Conditions on Catalytic Properties
Catalysts. 2022. V.12. N8. 878 :1-14. DOI: 10.3390/catal12080878 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Jun 28, 2022 |
| Accepted: | Aug 8, 2022 |
| Published print: | Aug 10, 2022 |
| Published online: | Sep 10, 2022 |
Identifiers:
| Web of science: | WOS:000847070600001 |
| Scopus: | 2-s2.0-85137370458 |
| Elibrary: | 52253280 |
| Chemical Abstracts: | 2022:2264042 |
| OpenAlex: | W4290988407 |