Tungsten Peroxopolyoxo Complexes – Promising Catalysts for Oxidation of Organic Compounds. II. Structure of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} Complex from the Small-Angle X-ray Scattering Data Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2022, Volume: 63, Number: 8, Pages: 1215-1223 Pages count : 9 DOI: 10.1134/S0022476622080029 | ||||
| Tags | peroxopolyoxo tungstenate complexes, quaternary ammonium cations, small angle X-ray scattering | ||||
| Authors |
|
||||
| Affiliations |
|
Funding (3)
| 1 | Russian Foundation for Basic Research | 19-03-00202 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0005 |
| 3 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0003 |
Abstract:
By small angle X-ray scattering (SAXS) solutions of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} peroxopolyoxo complex are studied using 13 different organic solvents. In solutions of heptane, cyclohexane, and diethyl ether, the peroxo complex is shown to form large aggregates. In a number of other solvents tested, the complex is present as individual molecules in the solution. The size of the molecules is 14.5±1.2 Å. Structural parameters of the complex are found, and a low resolution model of the structure is proposed.
Cite:
Larichev Y.V.
, Selivanova N.V.
, Berdnikova P.V.
, Pai Z.P.
Tungsten Peroxopolyoxo Complexes – Promising Catalysts for Oxidation of Organic Compounds. II. Structure of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} Complex from the Small-Angle X-ray Scattering Data
Journal of Structural Chemistry. 2022. V.63. N8. P.1215-1223. DOI: 10.1134/S0022476622080029 WOS Scopus РИНЦ AN OpenAlex
Tungsten Peroxopolyoxo Complexes – Promising Catalysts for Oxidation of Organic Compounds. II. Structure of the [(n-Oct)3NMe]3{PO4[WO(O2)2]4} Complex from the Small-Angle X-ray Scattering Data
Journal of Structural Chemistry. 2022. V.63. N8. P.1215-1223. DOI: 10.1134/S0022476622080029 WOS Scopus РИНЦ AN OpenAlex
Original:
Ларичев Ю.В.
, Селиванова Н.В.
, Бердникова П.В.
, Пай З.П.
Пероксополиоксокомплексы вольфрама - перспективные катализаторы окисления органических соединений. II. Структура комплекса [(N-Oct)3NME]3{PO4[WO(O2)2]4} по данным метода малоуглового рентгеновского рассеяния
Журнал структурной химии. 2022. Т.63. №8. 95215 :1-9. DOI: 10.26902/jsc_id95215 РИНЦ OpenAlex
Пероксополиоксокомплексы вольфрама - перспективные катализаторы окисления органических соединений. II. Структура комплекса [(N-Oct)3NME]3{PO4[WO(O2)2]4} по данным метода малоуглового рентгеновского рассеяния
Журнал структурной химии. 2022. Т.63. №8. 95215 :1-9. DOI: 10.26902/jsc_id95215 РИНЦ OpenAlex
Dates:
| Submitted: | Jan 12, 2022 |
| Accepted: | Mar 4, 2022 |
| Published print: | Aug 1, 2022 |
| Published online: | Sep 1, 2022 |
Identifiers:
| Web of science: | WOS:000848768400002 |
| Scopus: | 2-s2.0-85137530417 |
| Elibrary: | 50438316 |
| Chemical Abstracts: | 2022:2314973 |
| OpenAlex: | W4294097671 |