Novel MOF Catalysts Based on Calix[4]arene for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2 | Sciact - CRIS-system of Boreskov Institute of Catalysis

Novel MOF Catalysts Based on Calix[4]arene for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2 Full article

Journal

Journal of CO2 Utilization
ISSN: 2212-9820

Output data

Year: 2022, Volume: 66, Article number : 102262, Pages count : 10 DOI: 10.1016/j.jcou.2022.102262

Tags

Host-guest system NH2-MIL-101(Al)/Calix[4]arene; Composite; Propylene Carbonate; CO2; Propylene oxide

Authors

Isaeva Vera I. ¹ , Timofeeva Maria N. ^2,3 , Lukoyanov Ivan A. ^2,3 , Gerasimov Evgeny Yu. ² , Panchenko Valentina N. ³ , Chernyshev Vladimir V. ^4,5 , Glukhov Lev M. ¹ , Kustov Leonid M. ^1,6

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, RAS, Leninsky Prospect 47, Moscow 119991, Russian Federation
2	Boreskov Institute of Catalysis SB RAS, Prospect Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
3	Novosibirsk State Technical University, pr. K. Marks 20, 630092 Novosibirsk, Russian Federation
4	Chemistry Department, Moscow State University, Leninskie Gory 1, bldg. 3, Moscow 119992, Russia
5	A. N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 31 Leninsky Prospect, Moscow 119071, Russian Federation
6	National University of Science and Technology MISiS, Leninsky pospect 4, 119991, Russian Federation

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	0239-2021-0008
2	Ministry of Science and Higher Education of the Russian Federation	075-15-2021-591

In this study, novel composite materials based on calix[4]arene with hydroxyl groups in the arene “bowl” (K-OH) and the aluminum(III) 2-aminoterephthalate metal organic framework (NH2-MIL-101(Al), MIL) have been synthesized according to in situ or “bottle around ship” strategy. The effect of the synthesis method, i.e., MW-assisted technique (MW) and the solvothermal procedure (Solv), on the structural, morphological, textural and catalytic properties of MIL/K-OH composites was demonstrated. Catalytic performance of the MIL/K-OH(MW) and MIL/K-OH(Solv) composites was studied in solvent-free coupling of CO2 and propylene oxide (PO) to produce propylene carbonate (PC) at 0.8 MPa of CO2 and 80 oC. The activity of the MIL/K-OH(Solv) catalyst was higher in comparison with MIL/K-OH(MW) material as a result of the differences in the textural properties. The binary system MIL/K-OH(MW)/[n-Bu4N]Br was demonstrated to be a promising catalyst for cycloaddition of CO2 to PO. In its presence, the conversion of PO was 77% with 99% selectivity towards PC at 1.2 MPa of CO2, 50 oC for 24 h.

Isaeva V.I. , Timofeeva M.N. , Lukoyanov I.A. , Gerasimov E.Y. , Panchenko V.N. , Chernyshev V.V. , Glukhov L.M. , Kustov L.M.
Novel MOF Catalysts Based on Calix[4]arene for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2
Journal of CO2 Utilization. 2022. V.66. 102262 :1-10. DOI: 10.1016/j.jcou.2022.102262 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jul 10, 2022
Accepted:	Oct 6, 2022
Published online:	Oct 12, 2022
Published print:	Dec 1, 2022

Web of science:	WOS:000876516400002
Scopus:	2-s2.0-85140220258
Elibrary:	50768468
Chemical Abstracts:	2022:2678330
OpenAlex:	W4304701330

DB	Citing
Scopus	10
Web of science	10
Elibrary	9
OpenAlex	11