Sciact
  • EN
  • RU

Novel MOF Catalysts Based on Calix[4]arene for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2 Full article

Journal Journal of CO2 Utilization
ISSN: 2212-9820
Output data Year: 2022, Volume: 66, Article number : 102262, Pages count : 10 DOI: 10.1016/j.jcou.2022.102262
Tags Host-guest system NH2-MIL-101(Al)/Calix[4]arene; Composite; Propylene Carbonate; CO2; Propylene oxide
Authors Isaeva Vera I. 1 , Timofeeva Maria N. 2,3 , Lukoyanov Ivan A. 2,3 , Gerasimov Evgeny Yu. 2 , Panchenko Valentina N. 3 , Chernyshev Vladimir V. 4,5 , Glukhov Lev M. 1 , Kustov Leonid M. 1,6
Affiliations
1 N.D. Zelinsky Institute of Organic Chemistry, RAS, Leninsky Prospect 47, Moscow 119991, Russian Federation
2 Boreskov Institute of Catalysis SB RAS, Prospect Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
3 Novosibirsk State Technical University, pr. K. Marks 20, 630092 Novosibirsk, Russian Federation
4 Chemistry Department, Moscow State University, Leninskie Gory 1, bldg. 3, Moscow 119992, Russia
5 A. N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 31 Leninsky Prospect, Moscow 119071, Russian Federation
6 National University of Science and Technology MISiS, Leninsky pospect 4, 119991, Russian Federation

Funding (2)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0008
2 Ministry of Science and Higher Education of the Russian Federation 075-15-2021-591

Abstract: In this study, novel composite materials based on calix[4]arene with hydroxyl groups in the arene “bowl” (K-OH) and the aluminum(III) 2-aminoterephthalate metal organic framework (NH2-MIL-101(Al), MIL) have been synthesized according to in situ or “bottle around ship” strategy. The effect of the synthesis method, i.e., MW-assisted technique (MW) and the solvothermal procedure (Solv), on the structural, morphological, textural and catalytic properties of MIL/K-OH composites was demonstrated. Catalytic performance of the MIL/K-OH(MW) and MIL/K-OH(Solv) composites was studied in solvent-free coupling of CO2 and propylene oxide (PO) to produce propylene carbonate (PC) at 0.8 MPa of CO2 and 80 oC. The activity of the MIL/K-OH(Solv) catalyst was higher in comparison with MIL/K-OH(MW) material as a result of the differences in the textural properties. The binary system MIL/K-OH(MW)/[n-Bu4N]Br was demonstrated to be a promising catalyst for cycloaddition of CO2 to PO. In its presence, the conversion of PO was 77% with 99% selectivity towards PC at 1.2 MPa of CO2, 50 oC for 24 h.
Cite: Isaeva V.I. , Timofeeva M.N. , Lukoyanov I.A. , Gerasimov E.Y. , Panchenko V.N. , Chernyshev V.V. , Glukhov L.M. , Kustov L.M.
Novel MOF Catalysts Based on Calix[4]arene for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2
Journal of CO2 Utilization. 2022. V.66. 102262 :1-10. DOI: 10.1016/j.jcou.2022.102262 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Jul 10, 2022
Accepted: Oct 6, 2022
Published online: Oct 12, 2022
Published print: Dec 1, 2022
Identifiers:
Web of science: WOS:000876516400002
Scopus: 2-s2.0-85140220258
Elibrary: 50768468
Chemical Abstracts: 2022:2678330
OpenAlex: W4304701330
Citing:
DB Citing
Scopus 10
Web of science 10
Elibrary 9
OpenAlex 11
Altmetrics: