Formic Acid Production via One-Pot Hydrolysis-Oxidation of Starch over Quaternary Ammonium Salts of Vanadium-Containing Keggin-Type Heteropoly Acids Научная публикация
| Журнал |
Catalysts
ISSN: 2073-4344 |
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| Вых. Данные | Год: 2022, Том: 12, Номер: 10, Номер статьи : 1252, Страниц : 13 DOI: 10.3390/catal12101252 | ||
| Ключевые слова | one-pot; hydrolysis-oxidation; OxFA-process; starch; formic acid; bifunctional catalyst; Keggin-type vanadium-containing heteropoly acids | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский научный фонд | 17-73-30032 |
Реферат:
Bifunctional solid acidic quaternary ammonium salts of Keggin-type vanadium-containing heteropoly acids, such as R3.5H0.5PVMo11O40 (R: (C2H5)4N, (C4H9)4N, (C6H13)4N), and [(C4H9)4N]4.5H0.5SiW11VO40, are capable of one-pot hydrolysis-oxidationconversion (OxFA-processing) of starch to biogenic formic acid. The impact of the reaction conditions and catalyst type was revealed. The highest formic acid yield of 50% was achieved over the best [(C2H5)4N]3.5H0.5PVMo11O40 catalyst, which was active and stable in seven reaction cycles. The kinetic computational model, which described formic acid formation well, was proposed in the presence of the most active [(C2H5)4N]3.5H0.5PVMo11O40 catalyst.
Библиографическая ссылка:
Gromov N.V.
, Medvedeva T.B.
, Lukoyanov I.A.
, Panchenko V.N.
, Timofeeva M.N.
, Taran O.P.
, Parmon V.N.
Formic Acid Production via One-Pot Hydrolysis-Oxidation of Starch over Quaternary Ammonium Salts of Vanadium-Containing Keggin-Type Heteropoly Acids
Catalysts. 2022. V.12. N10. 1252 :1-13. DOI: 10.3390/catal12101252 WOS Scopus РИНЦ CAPlus OpenAlex
Formic Acid Production via One-Pot Hydrolysis-Oxidation of Starch over Quaternary Ammonium Salts of Vanadium-Containing Keggin-Type Heteropoly Acids
Catalysts. 2022. V.12. N10. 1252 :1-13. DOI: 10.3390/catal12101252 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 20 сент. 2022 г. |
| Принята к публикации: | 11 окт. 2022 г. |
| Опубликована в печати: | 17 окт. 2022 г. |
| Опубликована online: | 17 окт. 2022 г. |
Идентификаторы БД:
| Web of science: | WOS:000872486000001 |
| Scopus: | 2-s2.0-85140821794 |
| РИНЦ: | 50204670 |
| Chemical Abstracts: | 2022:2754250 |
| OpenAlex: | W4306403487 |