Solvent-Free Synthesis of Nickel Nanoparticles as Catalysts for CO2 Hydrogenation to Methane | Sciact - CRIS-system of Boreskov Institute of Catalysis

Solvent-Free Synthesis of Nickel Nanoparticles as Catalysts for CO2 Hydrogenation to Methane Full article

Journal

Catalysts
ISSN: 2073-4344

Output data

Year: 2022, Volume: 12, Number: 10, Article number : 1274, Pages count : 19 DOI: 10.3390/catal12101274

Tags

solvent-free synthesis; solid-state combustion; nickel; nanoparticle; catalyst; CO2 methanation

Authors

Netskina Olga V. ^1,2 , Dmitruk Kirill A. ^1,2 , Paletsky Alexander A. ^1,3 , Mukha Svetlana A. ¹ , Pochtar Alena A. ^1,2 , Bulavchenko Olga A. ¹ , Prosvirin Igor P. ¹ , Shmakov Andrey G. ³ , Ozerova Anna M. ^1,4 , Veselovskaya Janna V. ^1,2 , Mazina Olga I. ¹ , Komova Oxana V. ^1,4

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
2	Department of Natural Sciences, Novosibirsk State University, 1 Pirogova Str., 630090 Novosibirsk, Russia
3	Voevodsky Institute of Chemical Kinetics and Combustion SB RAS, 3 Institutskaya Str., 630090 Novosibirsk, Russia
4	Siberian Branch of Russian Academy of Sciences, Pr. Akademika Lavrentieva 17, 630090 Novosibirsk, Russia

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

075-15-2020-781

The solid-state combustion method was used to prepare nickel-based catalysts for CO2 hydrogenation from [Ni(C3H4N2)6](NO3)2 and [Ni(C3H4N2)6](ClO4)2. These complexes were synthesized by adding nickel nitrate and perchlorate to melted imidazole. The composition and structure of the obtained complexes was confirmed by ATR FTIR, powder XRD and elemental analysis. The stages of thermal decomposition of the complexes and their kinetic parameters were established. It was found that incomplete gasification of more thermostable Ni(C3H4N2)6](ClO4)2 led to the formation of carbon, nitrogen, and chlorine impurities. According to powder XRD and XPS, the solid products of gasification of both complexes consist of NiO and Ni0 covered with nickel hydroxide and/or carbonate layer. In the case of the sample prepared from [Ni(C3H4N2)6](ClO4)2 this layer is pronounced. Therefore, it limits the nickel reduction in the reaction medium of CO2 hydrogenation, even at 450 °C. The surface of the sample prepared from [Ni(C3H4N2)6](NO3)2 contains nickel oxide, which is easily reduced. So, catalyst active phase is already formed at 250 °C in the presence of CO2 and efficiently catalyzes CO2 hydrogenation as the temperature increases. Therefore, [Ni(C3H4N2)6](NO3)2 is a promising precursor for the CO2 hydrogenation catalyst, and its solvent-free synthesis follows Green Chemistry principles.

Netskina O.V. , Dmitruk K.A. , Paletsky A.A. , Mukha S.A. , Pochtar A.A. , Bulavchenko O.A. , Prosvirin I.P. , Shmakov A.G. , Ozerova A.M. , Veselovskaya J.V. , Mazina O.I. , Komova O.V.
Solvent-Free Synthesis of Nickel Nanoparticles as Catalysts for CO2 Hydrogenation to Methane
Catalysts. 2022. V.12. N10. 1274 :1-19. DOI: 10.3390/catal12101274 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Sep 29, 2022
Accepted:	Oct 18, 2022
Published print:	Oct 19, 2022
Published online:	Oct 19, 2022

Web of science:	WOS:000872681600001
Scopus:	2-s2.0-85140835160
Elibrary:	52469918
Chemical Abstracts:	2022:2754257
OpenAlex:	W4306836287

DB	Citing
Scopus	5
Web of science	5
Elibrary	4
OpenAlex	5