Nanomaterials with Oxygen Mobility for Catalysts of Biofuels Transformation into Syngas, SOFC and Oxygen/Hydrogen Separation Membranes: Design and Performance Научная публикация
| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2023, Том: 423, Номер статьи : 113936, Страниц : 29 DOI: 10.1016/j.cattod.2022.10.018 | ||||
| Ключевые слова | Structured catalysts, biofuels reforming, hydrogen and syngas, solid oxide fuel cells, hydrogen and oxygen separation membranes, oxygen mobility, perovskites, fluorites, spinel, nanocomposites, synthesis, characterization, oxygen isotope heteroexchange, performance | ||||
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0005 |
Реферат:
Modern hydrogen energy technologies include generation of syngas and pure hydrogen from biofuels to be used for green energy production in solid oxide fuel cells (SOFC). To be economically feasible, these processes require design of stable, efficient and inexpensive catalysts, permselective membranes for hydrogen and oxygen separation as well as SOFC cathode and anode materials. In all cases, such materials should possess a high oxygen mobility. This review presents results of our research devoted to design of materials based on complex oxides with fluorite, perovskite, and spinel structures used in these applications. The key aspect is characterization of their oxygen mobility by unique method of temperature –programmed oxygen heteroexchange in flow reactors and finding its dependence on their composition, real structure/microstructure and surface properties affected by methods of synthesis and elucidated with the help of modern structural, spectroscopic and kinetic methods. Optimized materials were shown to provide stable and efficient performance in catalytic reactors, membranes and solid oxide fuels cells.
Библиографическая ссылка:
Sadykov V.
, Eremeev N.
, Sadovskaya E.
, Bespalko Y.
, Simonov M.
, Arapova M.
, Smal E.
Nanomaterials with Oxygen Mobility for Catalysts of Biofuels Transformation into Syngas, SOFC and Oxygen/Hydrogen Separation Membranes: Design and Performance
Catalysis Today. 2023. V.423. 113936 :1-29. DOI: 10.1016/j.cattod.2022.10.018 WOS Scopus РИНЦ OpenAlex CAPlus
Nanomaterials with Oxygen Mobility for Catalysts of Biofuels Transformation into Syngas, SOFC and Oxygen/Hydrogen Separation Membranes: Design and Performance
Catalysis Today. 2023. V.423. 113936 :1-29. DOI: 10.1016/j.cattod.2022.10.018 WOS Scopus РИНЦ OpenAlex CAPlus
Даты:
| Поступила в редакцию: | 19 июн. 2022 г. |
| Принята к публикации: | 23 окт. 2022 г. |
| Опубликована online: | 28 окт. 2022 г. |
| Опубликована в печати: | 1 нояб. 2023 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:001063146900001 |
| ≡ Scopus: | 2-s2.0-85141263082 |
| ≡ РИНЦ: | 54352696 |
| ≡ OpenAlex: | W4307454586 |
| ≡ Chemical Abstracts: | 2022:2802428 |