Experimental Redetermination of the Cu–Pd Phase Diagram | Sciact - CRIS-system of Boreskov Institute of Catalysis

Experimental Redetermination of the Cu–Pd Phase Diagram Full article

Journal

Journal of Alloys and Compounds
ISSN: 0925-8388 , E-ISSN: 1873-4669

Output data

Year: 2018, Volume: 777, Pages: 204-212 Pages count : 9 DOI: 10.1016/j.jallcom.2018.10.332

Tags

Copper; Experimental X–ray study; Nanoalloys; Palladium; Phase diagram

Authors

Popov A.A. ¹ , Shubin Yu.V. ^1,2 , Plyusnin P.E. ^1,2 , Sharafutdinov M.R. ³ , Korenev S.V. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Institute of Solid State Chemistry and Mechanochemistry SB RAS, Russia

The equilibrium Cu–Pd phase diagram has been experimentally reinvestigated in the 300–680 °C temperature region by powder XRD involving a high-temperature technique. To reduce the annealing time needed for the system to attain the equilibrium state, nanosized specimens with a characteristic crystallite size of 5–15 nm were used initially. All previously reported phases, i.e., a disordered face-centered cubic solid solution Cu1-xPdx (A1), a one-dimensional long-period superlattice structure Cu21Pd7 (1D–LPS), intermetallic compounds Cu3Pd (L12) and CuPd (B2), except a two-dimensional long-period superlattice structure (2D–LPS), could be confirmed. Homogeneity ranges of all solid phases existing in the Cu–Pd system were determined at distinct temperatures. The largest deviation of the solubility limits was observed for the Pd-rich boundary of the Cu3Pd region (25–30 at.% Pd) and the Cu-rich boundary of the Cu1-xPdx region in the compositional range >55 at.% Pd. Based on the present experimental results, the constitutional Cu–Pd diagram was modified.

Popov A.A. , Shubin Y.V. , Plyusnin P.E. , Sharafutdinov M.R. , Korenev S.V.
Experimental Redetermination of the Cu–Pd Phase Diagram
Journal of Alloys and Compounds. 2018. V.777. P.204-212. DOI: 10.1016/j.jallcom.2018.10.332 WOS Scopus ANCAN OpenAlex

Submitted:	Aug 19, 2018
Accepted:	Oct 25, 2018
Published online:	Oct 27, 2018
Published print:	Mar 10, 2019

Web of science:	WOS:000454856800026
Scopus:	2-s2.0-85056182118
Chemical Abstracts:	2018:2116453
Chemical Abstracts (print):	170:20900
OpenAlex:	W2898176087

DB	Citing
Scopus	27
OpenAlex	26
Web of science	25