The Study of Thermal Stability of Mn-Zr-Ce, Mn-Ce and Mn-Zr Oxide Catalysts for CO Oxidation Full article
| Journal |
Materials
ISSN: 1996-1944 |
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| Output data | Year: 2022, Volume: 15, Number: 21, Article number : 7553, Pages count : 18 DOI: 10.3390/ma15217553 | ||||
| Tags | Mn-Ce; Mn-Zr; Mn-Zr-Ce; thermal stability; CO oxidation | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 21-73-10218 |
Abstract:
MnOx-CeO2, MnOx-ZrO2, MnOx-ZrO2-CeO2 oxides with the Mn/(Zr + Ce + Mn) molar ratio of 0.3 were synthesized by coprecipitation method followed by calcination in the temperature range of 400–800 °C and characterized by XRD, N2 adsorption, TPR, TEM, and EPR. The catalytic activity was tested in the CO oxidation reaction. It was found that MnOx-CeO2, MnOx-ZrO2-CeO2, MnOx-ZrO2 catalysts, calcined at 400–500 °C, 650–700 °C and 500–650 °C, respectively, show the highest catalytic activity in the reaction of CO oxidation. According to XRD and TEM results, thermal stability of catalysts is determined by the temperature of decomposition of the solid solution Mnx(Ce,Zr)1−xO2. The TPR-H2 and EPR methods showed that the high activity in CO oxidation correlates with the content of easily reduced fine MnOx particles in the samples and the presence of paramagnetic defects in the form of oxygen vacancies. The maximum activity for each series of catalysts is associated with the start of solid solution decomposition. Formation of active phase shifts to the high-temperature region with the addition of zirconium to the MnOx-CeO2 catalyst.
Cite:
Afonasenko T.N.
, Glyzdova D.V.
, Yurpalov V.L.
, Konovalova V.P.
, Rogov V.A.
, Gerasimov E.Y.
, Bulavchenko O.A.
The Study of Thermal Stability of Mn-Zr-Ce, Mn-Ce and Mn-Zr Oxide Catalysts for CO Oxidation
Materials. 2022. V.15. N21. 7553 :1-18. DOI: 10.3390/ma15217553 WOS Scopus РИНЦ OpenAlex AN PMID publication_identifier_short.sciact_ihcp_identifier_type
The Study of Thermal Stability of Mn-Zr-Ce, Mn-Ce and Mn-Zr Oxide Catalysts for CO Oxidation
Materials. 2022. V.15. N21. 7553 :1-18. DOI: 10.3390/ma15217553 WOS Scopus РИНЦ OpenAlex AN PMID publication_identifier_short.sciact_ihcp_identifier_type
Dates:
| Submitted: | Sep 19, 2022 |
| Accepted: | Oct 25, 2022 |
| Published online: | Oct 27, 2022 |
| Published print: | Nov 1, 2022 |
Identifiers:
| ≡ Web of science: | WOS:000882747100001 |
| ≡ Scopus: | 2-s2.0-85141871700 |
| ≡ Elibrary: | 50404635 |
| ≡ OpenAlex: | W4307704711 |
| ≡ Chemical Abstracts: | 2022:2868722 |
| ≡ PMID: | 36363144 |
| ≡ publication_identifier.sciact_ihcp_identifier_type: | 3854 |