Pd/CeO2-SnO2 Catalysts with Varying Tin Content: Promotion of Catalytic Properties and Structure Modification Full article
| Journal |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Output data | Year: 2022, Volume: 172, Article number : 106554, Pages count : 17 DOI: 10.1016/j.catcom.2022.106554 | ||||||
| Tags | CeO2; CO oxidation; Methane oxidation; Palladium; SnO2; Thermal stability | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0003 |
| 2 | The Ministry of Education and Science of the Russian Federation | FWUZ-2021-0002 (121031700315-2) |
Abstract:
1%Pd/CeO2-SnO2 catalysts with varying Ce/Sn ratio were synthesized by counter-precipitation followed by calcination in a wide temperature range. The catalysts with Ce/Sn < 3/1 possess high thermal stability after calcination up to 1000 °C while maintaining low-temperature activity in CO oxidation. The PdOx clusters serving as active centers in CO oxidation are modified by Sn upon calcination. High tin content (Ce/Sn = 1/3) provides the activity of the catalysts in CH4 oxidation due to stabilization of PdO nanoparticles in the form of core@shell PdO@(CeO2 + SnO2) structures. Formation of the nanoheterophase structure upon calcination plays a key role in the stabilization of Pd-active centers of different types. © 2022
Cite:
Stonkus O.A.
, Zadesenets A.V.
, Slavinskaya E.M.
, Stadnichenko A.I.
, Svetlichnyi V.A.
, Shubin Y.V.
, Korenev S.V.
, Boronin A.I.
Pd/CeO2-SnO2 Catalysts with Varying Tin Content: Promotion of Catalytic Properties and Structure Modification
Catalysis Communications. 2022. V.172. 106554 :1-17. DOI: 10.1016/j.catcom.2022.106554 WOS Scopus РИНЦ AN OpenAlex
Pd/CeO2-SnO2 Catalysts with Varying Tin Content: Promotion of Catalytic Properties and Structure Modification
Catalysis Communications. 2022. V.172. 106554 :1-17. DOI: 10.1016/j.catcom.2022.106554 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Sep 5, 2022 |
| Accepted: | Oct 30, 2022 |
| Published online: | Oct 31, 2022 |
| Published print: | Dec 1, 2022 |
Identifiers:
| Web of science: | WOS:000892539200005 |
| Scopus: | 2-s2.0-85141318448 |
| Elibrary: | 50420893 |
| Chemical Abstracts: | 2022:2819819 |
| OpenAlex: | W4307905920 |