Hydrogen Production through Bi-Reforming of Methane: Improving Ni Catalyst Performance via an Exsolution Approach | Sciact - CRIS-система Института катализа

Hydrogen Production through Bi-Reforming of Methane: Improving Ni Catalyst Performance via an Exsolution Approach Научная публикация

Журнал

Catalysts
ISSN: 2073-4344

Вых. Данные

Год: 2022, Том: 12, Номер: 12, Номер статьи : 1493, Страниц : 39 DOI: 10.3390/catal12121493

Ключевые слова

hydrogen; methane; bi-reforming; Ni catalyst; dopant; exsolution

Авторы

Matus Ekaterina ¹ , Sukhova Olga ¹ , Kerzhentsev Mikhail ¹ , Ismagilov Ilyas ¹ , Yashnik Svetlana ¹ , Ushakov Vladimir ¹ , Stonkus Olga ¹ , Gerasimov Evgeny ¹ , Nikitin Andrey ² , Bharali Pankaj ³ , Ismagilov Zinfer ^1,2

Организации

1	Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia
2	The Federal Research Center of Coal and Coal Chemistry, SB RAS, 650000 Kemerovo, Russia
3	Department of Chemical Sciences, Tezpur University, Napaam, Tezpur 784 028, Assam, India

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)

0239-2021-0004

Hydrogen production through the bi-reforming of methane over exsolution-derived Ni catalysts has been studied. Nickel-based catalysts were prepared through the activation of (CeM)1−xNixOy (M = Al, La, Mg) solid solutions in a reducing gaseous medium. Their performance and resistance to coking under the reaction conditions were controlled by regulating their textural, structural, morphological, and redox properties through adjustments to the composition of the oxide matrix (M/Ce = 0–4; x = 0.2–0.8; y = 1.0–2.0). The role of the M-dopant type in the genesis and properties of the catalysts was established. The efficiency of the catalysts in the bi-reforming of methane increased in the following series of M: M-free < La < Al < Mg, correlating with the structural behavior of the nickel active component and the anti-coking properties of the support matrix. The preferred M-type and M/Ce ratio determined the best performance of (CeM)1−xNixOy catalysts. At 800 °C the optimum Ce0.6Mg0.2Ni0.2O1.6 catalyst provided a stable H2 yield of 90% at a high level of CO2 and CH4 conversions (>85%).

Matus E. , Sukhova O. , Kerzhentsev M. , Ismagilov I. , Yashnik S. , Ushakov V. , Stonkus O. , Gerasimov E. , Nikitin A. , Bharali P. , Ismagilov Z.
Hydrogen Production through Bi-Reforming of Methane: Improving Ni Catalyst Performance via an Exsolution Approach
Catalysts. 2022. V.12. N12. 1493 :1-39. DOI: 10.3390/catal12121493 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	2 нояб. 2022 г.
Принята к публикации:	19 нояб. 2022 г.
Опубликована online:	22 нояб. 2022 г.
Опубликована в печати:	1 дек. 2022 г.

Web of science:	WOS:000902281300001
Scopus:	2-s2.0-85144938191
РИНЦ:	50344566
Chemical Abstracts:	2023:44065
OpenAlex:	W4309839646

БД	Цитирований
Web of science	13
Scopus	10
РИНЦ	13
OpenAlex	10