Reaction of Methane with Benzene and CO on Cu-Modified ZSM-5 Zeolite Investigated by 13C MAS NMR Spectroscopy Full article
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Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448 |
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| Output data | Year: 2023, Volume: 810, Article number : 140188, Pages count : 6 DOI: 10.1016/j.cplett.2022.140188 | ||
| Tags | Benzene methylation; Carbonylation with CO; Cu-modified ZSM-5 zeolite; Methane; Solid-state NMR | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0003 |
Abstract:
Three types of methoxy-like intermediates were generated at methane interaction with Cu-loaded ZSM-5 zeolite, containing copper in the form of either Cu2+ cations (Cu2+/H-ZSM-5) or [Cu3(µ-O)3]2+ oxo-clusters (CuO/H-ZSM-5). The methoxy species were tested for the reaction with benzene and carbon monoxide. 13C MAS NMR spectroscopy reveals that the methoxy species formed on CuO/H-ZSM-5 easily interact with benzene yielding toluene, whereas the methoxy species on Cu2+/H-ZSM-5 are less effective for benzene methylation. At the same time, the methoxy species on Cu2+/H-ZSM-5 can interact with CO forming surface acetate species, while strong adsorption of CO by [Cu3(µ-O)3]2+ oxo-clusters of CuO/H-ZSM-5 inhibits the reaction. © 2022 Elsevier B.V.
Cite:
Kolganov A.A.
, Gabrienko A.A.
, Stepanov A.G.
Reaction of Methane with Benzene and CO on Cu-Modified ZSM-5 Zeolite Investigated by 13C MAS NMR Spectroscopy
Chemical Physics Letters. 2023. V.810. 140188 :1-6. DOI: 10.1016/j.cplett.2022.140188 WOS Scopus РИНЦ AN OpenAlex
Reaction of Methane with Benzene and CO on Cu-Modified ZSM-5 Zeolite Investigated by 13C MAS NMR Spectroscopy
Chemical Physics Letters. 2023. V.810. 140188 :1-6. DOI: 10.1016/j.cplett.2022.140188 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Oct 7, 2022 |
| Accepted: | Nov 8, 2022 |
| Published online: | Nov 13, 2022 |
| Published print: | Jan 1, 2023 |
Identifiers:
| Web of science: | WOS:000929735400009 |
| Scopus: | 2-s2.0-85141960310 |
| Elibrary: | 54352593 |
| Chemical Abstracts: | 2022:2953532 |
| OpenAlex: | W4309783864 |