Kinetic Laws Governing Thermal Decomposition of Perchlorate Nickel Organometallic Complexes Under Changes of the Ligand Nature | Sciact - CRIS-система Института катализа

Kinetic Laws Governing Thermal Decomposition of Perchlorate Nickel Organometallic Complexes Under Changes of the Ligand Nature Научная публикация

Журнал

Journal of Engineering Physics and Thermophysics
ISSN: 1062-0125 , E-ISSN: 1573-871X

Вых. Данные

Год: 2022, Том: 95, Номер: 7, Страницы: 1732-1745 Страниц : 14 DOI: 10.1007/s10891-022-02644-2

Ключевые слова

organometallic complexes, ethylenediamine, imidazole, semicarbazide, perchlorate nickel, thermal decomposition kinetics

Авторы

Shmakov A.G. ¹ , Paletskii A.A. ¹ , Komova O.V. ² , Mukha S.A. ² , Dmitruk K.A. ² , Netskina O.V. ²

Организации

1	V. V. Voevodskii Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 Institutskaya Str., Novosibirsk, 630090, Russia
2	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 Academician Lavrentiev Ave., Novosibirsk, 630090, Russia

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)

075-15-2020-781

As a result of the interaction of nickel perchlorate with ethylenediamine, imidazole, and semicarbazide, complex compounds Ni(En)3(ClO4)2, Ni(Im)6(ClO4)2, and Ni(SC)3(ClO4)2 have been obtained, the structure and composition of which were confirmed by elemental analysis and by the method of the infrared spectroscopy of frustrated total internal reflection. The kinetics of the thermal decomposition of synthesized compounds in an inert medium was studied within the framework of the traditional method of thermal analysis in a helium atmosphere at a rate of the heating of samples of 5°C/min and under conditions of their high-speed heating (>100°C/min) with simultaneous determination of the composition of gaseous products of thermal decomposition of the material.

Shmakov A.G. , Paletskii A.A. , Komova O.V. , Mukha S.A. , Dmitruk K.A. , Netskina O.V.
Kinetic Laws Governing Thermal Decomposition of Perchlorate Nickel Organometallic Complexes Under Changes of the Ligand Nature
Journal of Engineering Physics and Thermophysics. 2022. V.95. N7. P.1732-1745. DOI: 10.1007/s10891-022-02644-2 WOS Scopus РИНЦ CAPlus OpenAlex

Шмаков А.Г. , Палецкий А.А. , Комова О.В. , Муха С.А. , Дмитрук К.А. , Нецкина О.В.
Кинетические закономерности термического разложения перхлоратных никелевых органометаллических комплексов при варьировании природы лиганда
Инженерно-физический журнал. 2022. Т.95. №7. С.1780-1793. РИНЦ

Поступила в редакцию:	9 дек. 2021 г.
Опубликована в печати:	5 дек. 2022 г.
Опубликована online:	5 дек. 2022 г.

Web of science:	WOS:000893888100006
Scopus:	2-s2.0-85143290918
РИНЦ:	50509237
Chemical Abstracts:	2022:3032459
OpenAlex:	W4310665590

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