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Novel 3D-Printed Alumina Monolith Catalysts for Hydroconversion of Tar Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532
Output data Year: 2022, Volume: 62, Number: 10, Pages: 1154–1161 Pages count : 8 DOI: 10.1134/S096554412210005X
Tags 3D printing, alumina, monolith catalyst, hydroconversion, tar
Authors Lysikov A.I. 1,2 , Vorobyeva E.E. 1,2 , Polukhin A.V. 1,2 , Lazarenko N.S. 1 , Vdovichenko V.A. 1,2 , Parkhomchuk E.V. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences (BIC SB RAS), Novosibirsk, 630090 Russia
2 Novosibirsk State University, Novosibirsk, 630090 Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0004

Abstract: This paper reports on a novel method for the preparation of monolith catalysts using a 3D-printed matrix. The development included an investigation into potential approaches to improving the strength of alumina catalysts, 3D printing of a polymer matrix (template) with a specific channel structure, preparation of templated monolith catalysts, an examination of their physicochemical properties, and testing of these catalysts in hydroconversion of tar. Using an indirect template method, this study is the first to prepare a Al2O3 monolith catalyst with a Schwartz surface microstructure. The extrudate drying rate was found to be the most important parameter for the synthesis of high-strength catalysts. The activity of the monolith catalyst proved to be comparable—and in some parameters even markedly superior—to that of similar granular samples. The tar hydroconversion product consisted of super heavy oil with 2.8 wt % of sulfur.
Cite: Lysikov A.I. , Vorobyeva E.E. , Polukhin A.V. , Lazarenko N.S. , Vdovichenko V.A. , Parkhomchuk E.V.
Novel 3D-Printed Alumina Monolith Catalysts for Hydroconversion of Tar
Petroleum Chemistry. 2022. V.62. N10. P.1154–1161. DOI: 10.1134/S096554412210005X WOS Scopus РИНЦ AN OpenAlex
Original: Лысиков А.И. , Воробьева Е.Е. , Полухин А.В. , Лазаренко Н.С. , Вдовиченко В.А. , Пархомчук Е.В.
Новые блочные алюмооксидные катализаторы, приготовленные методом 3D-печати, для процесса гидропереработки гудрона
Нефтехимия. 2022. Т.62. №6. С.816-824. DOI: 10.31857/S0028242122060041 РИНЦ OpenAlex
Dates:
Submitted: Jul 13, 2022
Published print: Oct 1, 2022
Accepted: Nov 11, 2022
Published online: Dec 14, 2022
Identifiers:
Web of science: WOS:000898672200003
Scopus: 2-s2.0-85143913229
Elibrary: 50328637
Chemical Abstracts: 2022:3100487
OpenAlex: W4311263607
Citing:
DB Citing
Scopus 1
Web of science 1
Elibrary 4
OpenAlex 1
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