In situ FTIR Study of Surface Site Transformations in Pd3In/α-Al2O3 and Pd3Ag/α-Al2O3 Induced by CO Adsorption | Sciact - CRIS-system of Boreskov Institute of Catalysis

In situ FTIR Study of Surface Site Transformations in Pd3In/α-Al2O3 and Pd3Ag/α-Al2O3 Induced by CO Adsorption ArticleGenre_short.SHORT_COMMUNICATION

Journal

Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X

Output data

Year: 2022, Volume: 32, Number: 6, Pages: 807-809 Pages count : 3 DOI: 10.1016/j.mencom.2022.11.033

Tags

adsorbate-induced segregation; Pd–Ag solid solution; palladium-based alloy; Pd–In intermetallics; DRIFT spectroscopy; of adsorbed CO

Authors

Smirnova Nadezhda S. ¹ , Baeva Galina N. ¹ , Markov Pavel V. ¹ , Mashkovsky Igor S. ¹ , Bukhtiyarov Andrey V. ² , Zubavichus Yan V. ² , Stakheev Alexander Yu. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Funding (1)

Russian Science Foundation

19-13-00285-П

In the course of the treatment of Pd3Ag/α-Al2O3 in 0.5%CO + He at 200 °C, intense transformation of single atom Pd1 surface sites isolated from each other by Ag atoms to multiatomic Pdn (n ≥ 2) ensembles occurs, as revealed by a rapid increase in the intensity of multibonded CO bands in FTIR spectra. The structure of intermetallic Pd3In nanoparticles is significantly more stable, and the formation of new multiatomic adsorption centers was not observed even after extended CO exposures.

Smirnova N.S. , Baeva G.N. , Markov P.V. , Mashkovsky I.S. , Bukhtiyarov A.V. , Zubavichus Y.V. , Stakheev A.Y.
In situ FTIR Study of Surface Site Transformations in Pd3In/α-Al2O3 and Pd3Ag/α-Al2O3 Induced by CO Adsorption
Mendeleev Communications. 2022. V.32. N6. P.807-809. DOI: 10.1016/j.mencom.2022.11.033 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jun 2, 2022
Published print:	Nov 1, 2022
Published online:	Nov 28, 2022

Web of science:	WOS:000892210700033
Scopus:	2-s2.0-85143141445
Elibrary:	50368191
Chemical Abstracts:	2022:3027273
OpenAlex:	W4310170712

DB	Citing
Scopus	10
Web of science	10
Elibrary	7
OpenAlex	7