Cadmium Sulfide Quantum Dots in Water Media: Enhanced Photoluminescence, Dispersion and Stability | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cadmium Sulfide Quantum Dots in Water Media: Enhanced Photoluminescence, Dispersion and Stability Full article

Journal

Journal of Molecular Liquids
ISSN: 0167-7322 , E-ISSN: 1873-3166

Output data

Year: 2023, Volume: 371, Article number : 121084, Pages count : 11 DOI: 10.1016/j.molliq.2022.121084

Tags

CdS; quantum dots; ligand shell; colloidal stability; luminescence

Authors

Kuznetsova Yulia V. ¹ , Popov Ivan D. ¹ , Gerasimov Evgeny ² , Rempel Andrey A. ^3,4

Affiliations

1	Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences, 620990 Ekaterinburg, Pervomaiskaya Str., 91, Russia
2	Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Lavrentieva Str. 5, Russia
3	Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, 620016 Ekaterinburg, Amundsena St. 101, Russia
4	Ural Federal University, 620002 Ekaterinburg, Mira St. 19, Russia

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

Within the presented study, we have investigated the effect of the ligand shell on the stability and optical properties of cadmium sulfide (CdS) quantum dots in a water colloidal solution stabilized by 3-mercaptopropyltrimethoxysilane (MPS). The correlation between stability and parameters of nanoparticles, namely, hydrodynamic radius, nucleus size and zeta-potential has been established. The optimal synthesis conditions of stable colloidal solutions shown the luminescence have been found. The mechanism of structural organization of the organic MPS shell, its bonding to the semiconductor nanoparticle surface and influence on the agglomeration has been developed. The mechanism of MPS capped CdS QDs luminescence switch on in water solution by pH control was proposed.

Kuznetsova Y.V. , Popov I.D. , Gerasimov E. , Rempel A.A.
Cadmium Sulfide Quantum Dots in Water Media: Enhanced Photoluminescence, Dispersion and Stability
Journal of Molecular Liquids. 2023. V.371. 121084 :1-11. DOI: 10.1016/j.molliq.2022.121084 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Sep 26, 2022
Accepted:	Dec 14, 2022
Published online:	Dec 17, 2022
Published print:	Feb 1, 2023

Web of science:	WOS:000917373200001
Scopus:	2-s2.0-85145667702
Elibrary:	54068260
Chemical Abstracts:	2022:3186687
OpenAlex:	W4312083056

DB	Citing
Scopus	2
Web of science	2
Elibrary	3
OpenAlex	4