Dehalogenative Aromatization of Perchlorofluoroalicyclic Compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the Vapour Phase or in Solution Full article
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Journal of Fluorine Chemistry
ISSN: 0022-1139 |
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| Output data | Year: 2004, Volume: 125, Number: 10, Pages: 1431-1435 Pages count : 5 DOI: 10.1016/j.jfluchem.2004.04.015 | ||
| Tags | Dehalogenation; Hexafluorobenzene; Octafluoronaphthalene; Pentafluoropyridine | ||
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Abstract:
Dehalogenation of perhalogenated cyclohexanes C6Cl6F6, 1-azacyclohexenes C5Cl4F5N and bicyclo[4.4.0]dec-1(6)-enes C10Cl8F8 in the vapour phase over iron filings at 350–500 °C and in solution with Zn and additivities (Cu, NiCl2·6H2O + bpy) at 80 °C (heterogeneous reaction) or with P(NEt2)3 at 20 °C (homogeneous reaction) was studied. In all cases, perfluoroarenes, chloroperfluoroarenes and dichloroperfluoroarenes (benzenes, naphthalenes and pyridines) were obtained in good overall yield.
Cite:
Bardin V.V.
, Trukhin D.V.
, Adonin N.Y.
, Starichenko V.F.
Dehalogenative Aromatization of Perchlorofluoroalicyclic Compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the Vapour Phase or in Solution
Journal of Fluorine Chemistry. 2004. V.125. N10. P.1431-1435. DOI: 10.1016/j.jfluchem.2004.04.015 WOS Scopus РИНЦ OpenAlex
Dehalogenative Aromatization of Perchlorofluoroalicyclic Compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the Vapour Phase or in Solution
Journal of Fluorine Chemistry. 2004. V.125. N10. P.1431-1435. DOI: 10.1016/j.jfluchem.2004.04.015 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Jan 30, 2004 |
| Accepted: | Apr 16, 2004 |
| Published online: | Jun 25, 2004 |
| Published print: | Oct 1, 2004 |
Identifiers:
| Web of science: | WOS:000224445400005 |
| Scopus: | 2-s2.0-4644281650 |
| Elibrary: | 13473421 |
| OpenAlex: | W1965891959 |