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Photocatalytic Activity of Titanium Dioxide Produced by High-Energy Milling Full article

Journal Наносистемы: физика, химия, математика = Nanosystems: physics, chemistry, mathematics
ISSN: 2220-8054 , E-ISSN: 2305-7971
Output data Year: 2022, Volume: 13, Number: 6, Pages: 632-639 Pages count : 8 DOI: 10.17586/2220-8054-2022-13-6-632-639
Tags Titanium dioxide, high-energy ball milling, photocatalytic oxidation
Authors Kozlova Ekaterina A. 1,2 , Valeeva Albina A. 3 , Sushnikova Anna A. 1 , Zhurenok Angelina V. 2 , Rempel Andrey A. 1
Affiliations
1 Institute of Metallurgy, UB RAS, Yekaterinburg, 620016, Russia
2 Boreskov Institute of Catalysis, SB RAS, Novosibirsk, 630090, Russia
3 Institute of Solid State Chemistry, UB RAS, Yekaterinburg, 620108, Russia

Funding (1)

1 Russian Science Foundation 21-73-20039 (121052500130-8)

Abstract: In this work, photocatalysts based on titanium dioxide were synthesized by high-energy ball milling of commercial titanium dioxide in the anatase modification. Using a complex of physicochemical methods, including XRD, low-temperature nitrogen adsorption, XPS and TEM, it was shown that the milling of commercial anatase leads to phase transformations and the formation of several phases of titanium dioxide, namely the high-pressure phase, the monoclinic phase of anatase and rutile, except for in addition, there is a change in the crystalline size and the value of the specific surface area grows from 8 to 31 m2/g. It was found that defects are introduced into the system during ball milling. The photocatalysts obtained by milling showed an activity comparable to the commercial standard TiO2 Degussa P25 in the destruction of the methylene blue dye under the action of UV light, while the adsorption properties of the synthesized samples exceeded those of commercial P25.
Cite: Kozlova E.A. , Valeeva A.A. , Sushnikova A.A. , Zhurenok A.V. , Rempel A.A.
Photocatalytic Activity of Titanium Dioxide Produced by High-Energy Milling
Наносистемы: физика, химия, математика = Nanosystems: physics, chemistry, mathematics. 2022. V.13. N6. P.632-639. DOI: 10.17586/2220-8054-2022-13-6-632-639 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Nov 1, 2022
Accepted: Nov 26, 2022
Published online: Dec 31, 2022
Identifiers:
Web of science: WOS:000907636200006
Scopus: 2-s2.0-85145399533
Elibrary: 50014594
Chemical Abstracts: 2023:1020446
OpenAlex: W4313395002
Citing:
DB Citing
Scopus 9
Elibrary 11
Web of science 7
OpenAlex 6
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