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Synthesis of Co-Ni Alloy Particles with the Structure of a Solid Substitution Solution by Precipitation in a Supercritical Carbon Dioxide Full article

Journal Nanomaterials
, E-ISSN: 2079-4991
Output data Year: 2022, Volume: 12, Number: 24, Article number : 4366, Pages count : 15 DOI: 10.3390/nano12244366
Tags supercritical fluids; Co-Ni alloy; solid substitution solution
Authors Nesterov Nikolay 1 , Pakharukova Vera 1 , Cherepanova Svetlana 1 , Yakushkin Stanislav 1 , Gerasimov Evgeniy 1 , Balaev Dmitry 2,3 , Semenov Sergei 2,3 , Dubrovskii Andrey 2,3 , Martyanov Oleg 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia
2 Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 660036 Krasnoyarsk, Russia
3 Institute of Engineering Physics and Radioelectronics, Siberian Federal University, 660041 Krasnoyarsk, Russia

Funding (1)

1 Russian Science Foundation 21-73-00213

Abstract: Mixed Co-Ni bimetallic systems with the structure of a solid substitution solution have been synthesized using the supercritical antisolvent precipitation (SAS) method, which uses supercritical CO2 as an antisolvent. The systems obtained have been characterized in detail using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), Fourier-transform infrared (FTIR) spectroscopy, and magnetostatic measurements. It has been found that Co-enriched systems have a defective hexagonal close-packed (hcp) structure, which was described by a model which embedded cubic fragments of packaging into a hexagonal close-packed (hcp) structure. It has been shown that an increase in water content at the precipitation stage leads to a decrease in the size of cubic fragments and a more uniform distribution of them in Co-enriched systems. It has also been shown that mixed systems have the greatest coercivity in the line of samples. Ni-enriched bimetallic systems have a cubic close-packed (ccp) structure with modified crystal lattice parameters.
Cite: Nesterov N. , Pakharukova V. , Cherepanova S. , Yakushkin S. , Gerasimov E. , Balaev D. , Semenov S. , Dubrovskii A. , Martyanov O.
Synthesis of Co-Ni Alloy Particles with the Structure of a Solid Substitution Solution by Precipitation in a Supercritical Carbon Dioxide
Nanomaterials. 2022. V.12. N24. 4366 :1-15. DOI: 10.3390/nano12244366 WOS Scopus РИНЦ AN PMID OpenAlex
Dates:
Submitted: Oct 31, 2022
Accepted: Dec 2, 2022
Published print: Dec 7, 2022
Published online: Dec 7, 2022
Identifiers:
Web of science: WOS:000904510200001
Scopus: 2-s2.0-85144886521
Elibrary: 50361382
Chemical Abstracts: 2023:45076
PMID: 36558218
OpenAlex: W4311858870
Citing:
DB Citing
Scopus 5
Web of science 5
Elibrary 4
OpenAlex 5
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