Iridium-Containing Automotive Emission Control Catalysts Full article
| Journal |
Doklady Physical Chemistry
ISSN: 0012-5016 , E-ISSN: 1608-3121 |
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| Output data | Year: 2022, Volume: 506, Number: 2, Pages: 131-137 Pages count : 7 DOI: 10.1134/S0012501622600218 | ||||
| Tags | alloys, iridium, palladium, rhodium, three-way catalysts, alumina, CO oxidation | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0010 |
| 2 | Russian Science Foundation | 21-13-00414 (121041300222-6) |
Abstract:
The possibility of partial replacement of rhodium by iridium in palladium–rhodium bimetallic nanoparticles acting as active sites of three-way catalysts has been studied. Pd–Ir–Rh trimetallic alloy particles were obtained by the thermolysis of a solid solution of double complex salts containing palladium and the second metal (iridium or rhodium) under reducing conditions. It has been determined that all the three metals are uniformly distributed in the bulk of the catalyst in places of location of alloy nanoparticles. The trimetallic catalyst samples are not inferior in thermal stability to the bimetallic catalyst Pd–Rh/-Al2O3, provided that iridium is incorporated into the active cluster as Ir3+ ions. The partial replacement of rhodium by iridium reduces the cost of the new material.
Cite:
Vedyagin A.A.
, Stoyanovskii V.O.
, Kenzhin R.M.
, Plyusnin P.E.
, Shubin Y.V.
Iridium-Containing Automotive Emission Control Catalysts
Doklady Physical Chemistry. 2022. V.506. N2. P.131-137. DOI: 10.1134/S0012501622600218 WOS Scopus РИНЦ AN OpenAlex
Iridium-Containing Automotive Emission Control Catalysts
Doklady Physical Chemistry. 2022. V.506. N2. P.131-137. DOI: 10.1134/S0012501622600218 WOS Scopus РИНЦ AN OpenAlex
Original:
Ведягин А.А.
, Стояновский В.О.
, Кенжин Р.М.
, Плюснин П.Е.
, Шубин Ю.В.
Иридий-содержащие катализаторы нейтрализации автомобильных выхлопов
Доклады Российской академии наук. Химия, науки о материалах (Доклады Академии наук до 2019 года). 2022. Т.506. С.57-64. DOI: 10.31857/S2686953522600477 РИНЦ OpenAlex
Иридий-содержащие катализаторы нейтрализации автомобильных выхлопов
Доклады Российской академии наук. Химия, науки о материалах (Доклады Академии наук до 2019 года). 2022. Т.506. С.57-64. DOI: 10.31857/S2686953522600477 РИНЦ OpenAlex
Dates:
| Submitted: | Jul 6, 2022 |
| Accepted: | Aug 25, 2022 |
Identifiers:
| Web of science: | WOS:000935887600001 |
| Scopus: | 2-s2.0-85148705755 |
| Elibrary: | 50768292 |
| Chemical Abstracts: | 2023:357212 |
| OpenAlex: | W4321383589 |