H2O2-Based Selective Oxidations Catalyzed by Supported Polyoxometalates: Recent Advances Обзор
| Журнал |
Catalysts
ISSN: 2073-4344 |
||
|---|---|---|---|
| Вых. Данные | Год: 2023, Том: 13, Номер: 2, Номер статьи : 360, Страниц : 28 DOI: 10.3390/catal13020360 | ||
| Ключевые слова | heterogeneous catalysis; hydrogen peroxide; immobilization; liquid-phase selective oxidation; polyoxometalates; supported catalysts | ||
| Авторы |
|
||
| Организации |
|
Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | 0239-2021-0009 |
Реферат:
Polyoxometalates (POMs) are transition metal oxygen anionic clusters that are oxidatively and thermally robust due to their inorganic, metal oxide-like nature. The versatility of their structures and compositions ensures tunable acid and redox properties, solubility, and functionality. The potential of POMs as homogeneous catalysts and building blocks for the construction of heterogeneous selective oxidations catalysts is being intensively investigated. POM catalysts immobilized on solid supports have the clear advantages of easy separation and reuse and, thus, better meet the requests of sustainable chemistry, provided that they are leaching-resistant under the reaction conditions. Here, we give a brief overview of recent advances in the field of liquid-phase selective oxidation of organic compounds using supported POMs and the green oxidant–hydrogen peroxide, with a focus on the critical issues of the catalyst stability and reusability. The scope and limitations of various approaches to POM immobilization are discussed.
Библиографическая ссылка:
Maksimchuk N.V.
, Kholdeeva O.A.
H2O2-Based Selective Oxidations Catalyzed by Supported Polyoxometalates: Recent Advances
Catalysts. 2023. V.13. N2. 360 :1-28. DOI: 10.3390/catal13020360 WOS Scopus РИНЦ CAPlus OpenAlex
H2O2-Based Selective Oxidations Catalyzed by Supported Polyoxometalates: Recent Advances
Catalysts. 2023. V.13. N2. 360 :1-28. DOI: 10.3390/catal13020360 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 16 дек. 2022 г. |
| Принята к публикации: | 2 февр. 2023 г. |
| Опубликована в печати: | 6 февр. 2023 г. |
| Опубликована online: | 6 февр. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:000944835200001 |
| Scopus: | 2-s2.0-85148962851 |
| РИНЦ: | 54787091 |
| Chemical Abstracts: | 2023:433324 |
| OpenAlex: | W4319441245 |