Highly Dispersed Ni on Nitrogen-Doped Carbon for Stable and Selective Hydrogen Generation from Gaseous Formic Acid | Sciact - CRIS-система Института катализа

Highly Dispersed Ni on Nitrogen-Doped Carbon for Stable and Selective Hydrogen Generation from Gaseous Formic Acid Научная публикация

Журнал

Nanomaterials
, E-ISSN: 2079-4991

Вых. Данные

Год: 2023, Том: 13, Номер: 3, Номер статьи : 545, Страниц : 18 DOI: 10.3390/nano13030545

Ключевые слова

N-doped carbon; Ni single-atom catalyst; Ni clusters; Ni nanoparticles; formic acid; hydrogen production

Авторы

Nishchakova Alina D. ¹ , Bulushev Dmitri A. ² , Trubina Svetlana V. ¹ , Stonkus Olga A. ² , Shubin Yury V. ¹ , Asanov Igor P. ¹ , Kriventsov Vladimir V. ² , Okotrub Alexander V. ¹ , Bulusheva Lyubov G. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia
2	Boreskov Institute of Catalysis SB RAS, 5 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia

Информация о финансировании (2)

1	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	0239-2021-0005
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	FWUZ-2021-0006 (121031700314-5)

Ni supported on N-doped carbon is rarely studied in traditional catalytic reactions. To fill this gap, we compared the structure of 1 and 6 wt% Ni species on porous N-free and N-doped carbon and their efficiency in hydrogen generation from gaseous formic acid. On the N-free carbon support, Ni formed nanoparticles with a mean size of 3.2 nm. N-doped carbon support contained Ni single-atoms stabilized by four pyridinic N atoms (N4-site) and sub-nanosized Ni clusters. Density functional theory calculations confirmed the clustering of Ni when the N4-sites were fully occupied. Kinetic studies revealed the same specific Ni mass-based reaction rate for single-atoms and clusters. The N-doped catalyst with 6 wt% of Ni showed higher selectivity in hydrogen production and did not lose activity as compared to the N-free 6 wt% Ni catalyst. The presented results can be used to develop stable Ni catalysts supported on N-doped carbon for various reactions.

Nishchakova A.D. , Bulushev D.A. , Trubina S.V. , Stonkus O.A. , Shubin Y.V. , Asanov I.P. , Kriventsov V.V. , Okotrub A.V. , Bulusheva L.G.
Highly Dispersed Ni on Nitrogen-Doped Carbon for Stable and Selective Hydrogen Generation from Gaseous Formic Acid
Nanomaterials. 2023. V.13. N3. 545 :1-18. DOI: 10.3390/nano13030545 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex

Поступила в редакцию:	20 дек. 2022 г.
Принята к публикации:	28 янв. 2023 г.
Опубликована online:	29 янв. 2023 г.
Опубликована в печати:	1 февр. 2023 г.

Web of science:	WOS:000931347500001
Scopus:	2-s2.0-85147908842
РИНЦ:	53903944
Chemical Abstracts:	2023:341444
Chemical Abstracts (print):	182:79465
PMID (PubMed):	36770506
OpenAlex:	W4318587502

БД	Цитирований
Scopus	8
Web of science	7
РИНЦ	4
OpenAlex	6