Insights into the Structure–Property–Activity Relationship of Zeolitic Imidazolate Frameworks for Acid–Base Catalysis Full article
| Journal |
International Journal of Molecular Sciences
ISSN: 1422-0067 , E-ISSN: 1661-6596 |
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| Output data | Year: 2023, Volume: 25, Number: 5, Article number : 4370, Pages count : 20 DOI: 10.3390/ijms24054370 | ||||
| Tags | zeolitic imidazolate frameworks; acid–base properties; structural impact; chemical composition impact; particle size effect; catalytic properties | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0008 |
| 2 | National Research Foundation of Korea | NRF-2020R1A4A1018393 |
Abstract:
Zeolitic imidazolate frameworks (ZIFs) have been extensively examined for their potential in acid–base catalysis. Many studies have demonstrated that ZIFs possess unique structural and physicochemical properties that allow them to demonstrate high activity and yield products with high selectivity. Herein, we highlight the nature of ZIFs in terms of their chemical formulation and the textural, acid–base, and morphological properties that strongly affect their catalytic performance. Our primary focus is the application of spectroscopic methods as instruments for analyzing the nature of active sites because these methods can allow an understanding of unusual catalytic behavior from the perspective of the structure–property–activity relationship. We examine several reactions, such as condensation reactions (the Knoevenagel condensation and Friedländer reactions), the cycloaddition of CO2 to epoxides, the synthesis of propylene glycol methyl ether from propylene oxide and methanol, and the cascade redox condensation of
2-nitroanilines with benzylamines. These examples illustrate the broad range of potentially promising applications of Zn–ZIFs as heterogeneous catalysts.
Cite:
Timofeeva M.N.
, Panchenko V.N.
, Jhung S.H.
Insights into the Structure–Property–Activity Relationship of Zeolitic Imidazolate Frameworks for Acid–Base Catalysis
International Journal of Molecular Sciences. 2023. V.25. N5. 4370 :1-20. DOI: 10.3390/ijms24054370 WOS Scopus РИНЦ AN PMID OpenAlex
Insights into the Structure–Property–Activity Relationship of Zeolitic Imidazolate Frameworks for Acid–Base Catalysis
International Journal of Molecular Sciences. 2023. V.25. N5. 4370 :1-20. DOI: 10.3390/ijms24054370 WOS Scopus РИНЦ AN PMID OpenAlex
Dates:
| Submitted: | Dec 30, 2022 |
| Accepted: | Feb 4, 2023 |
| Published online: | Feb 22, 2023 |
| Published print: | Mar 1, 2023 |
Identifiers:
| Web of science: | WOS:000947431900001 |
| Scopus: | 2-s2.0-85149900939 |
| Elibrary: | 54088903 |
| Chemical Abstracts: | 2023:545045 |
| PMID: | 36901801 |
| OpenAlex: | W4321598900 |