Design of Improved CoMo Hydrotreating Catalyst via Engineering of Carbon Nanotubes@Alumina Composite Support Full article
| Journal |
Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883 |
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| Output data | Year: 2023, Volume: 328, Article number : 122475, Pages count : 16 DOI: 10.1016/j.apcatb.2023.122475 | ||||||
| Tags | CoMo catalyst, Multi-walled carbon nanotubes, Alumina, Composite support, Hydrotreating | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0010 |
| 2 | Russian Science Foundation | 21-73-10039 (121091600012-5) |
Abstract:
An efficient strategy for the synthesis of nanostructured composite supports for CoMoS hydrotreating catalysts has been proposed. The synthesis concept is based on the growth of multi-walled carbon nanotubes (MWCNTs) on alumina crystallites modified with Fe2Co nanoparticles. The morphology and structural characteristics of the obtained MWCNT@Al2O3 supports were tuned by varying Fe2Co content. A comprehensive analysis using advanced techniques revealed the optimal content and structural characteristics of MWCNTs in composite supports that positively affect the morphology of the sulfide component. It has been established that for the best CoMoS/MWCNT@Al2O3 catalyst, which is characterized by the highest dispersion of sulfide component and CoMoS phase content, the activity in dibenzothiophene hydrodesulfurization and quinoline hydrodenitrogenation significantly exceeds the activity of CoMoS/Al2O3 and CoMoS/MWCNT catalysts. The proposed approach can be applied to improve the activity of both conventionally used hydrotreating catalysts and catalysts for other practically important processes by carefully tuning metal-support interaction.
Cite:
Kazakova M.A.
, Vatutina Y.V.
, Selyutin A.G.
, Prosvirin I.P.
, Gerasimov E.Y.
, Klimov O.V.
, Noskov A.S.
, Kazakov M.O.
Design of Improved CoMo Hydrotreating Catalyst via Engineering of Carbon Nanotubes@Alumina Composite Support
Applied Catalysis B: Environmental. 2023. V.328. 122475 :1-16. DOI: 10.1016/j.apcatb.2023.122475 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_skif_identifier_type
Design of Improved CoMo Hydrotreating Catalyst via Engineering of Carbon Nanotubes@Alumina Composite Support
Applied Catalysis B: Environmental. 2023. V.328. 122475 :1-16. DOI: 10.1016/j.apcatb.2023.122475 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_skif_identifier_type
Dates:
| Submitted: | Nov 20, 2022 |
| Accepted: | Feb 15, 2023 |
| Published online: | Feb 16, 2023 |
| Published print: | Jul 5, 2023 |
Identifiers:
| Web of science: | WOS:001007465500001 |
| Scopus: | 2-s2.0-85149742905 |
| Elibrary: | 54036595 |
| Chemical Abstracts: | 2023:386440 |
| OpenAlex: | W4321073674 |
| publication_identifier.sciact_skif_identifier_type: | 2223 |