Reductive Catalytic Fractionation of Abies Wood into Bioliquids and Cellulose with Hydrogen in an Ethanol Medium over NiCuMo/SiO2 Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Reductive Catalytic Fractionation of Abies Wood into Bioliquids and Cellulose with Hydrogen in an Ethanol Medium over NiCuMo/SiO2 Catalyst Full article

Journal

Catalysts
ISSN: 2073-4344

Output data

Year: 2023, Volume: 13, Number: 2, Article number : 413, Pages count : 19 DOI: 10.3390/catal13020413

Tags

abies wood; fractionation; hydrogenation with hydrogen; ethanol; catalyst; NiCuMo/SiO2; alkyl derivatives of methoxyphenols; cellulose

Authors

Kuznetsov Boris N. ^1,2 , Miroshnikova Angelina V. ^1,2 , Kazachenko Aleksandr S. ^1,2 , Baryshnikov Sergey V. ¹ , Malyar Yuriy N. ^1,2 , Yakovlev Vadim A. ³ , Skripnikov Andrey M. ^1,2 , Fetisova Olga Yu. ¹ , Xu Yong ⁴ , Taran Oxana P. ^1,2

Affiliations

1	Institute of Chemistry and Chemical Technology, Federal Research Center “Krasnoyarsk Science Center SB RAS”, Akademgorodok 50/24, Krasnoyarsk 660041, Russia
2	Department of Organic and Analytical Chemistry, Institute of Non-Ferrous Metals and Material Science, Siberian Federal University, Pr. Svobodny 79, Krasnoyarsk 660041, Russia
3	Federal Research Center “Boreskov Institute of Catalysis”, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia
4	College of Chemical Engineering, Nanjing Forestry University, No. 159 Longpan Road, Nanjing 210037, China

Funding (1)

Russian Science Foundation

21-13-00250

Noble metal-based catalysts are widely used to intensify the processes of reductive fractionation of lignocellulose biomass. In the present investigation, we proposed for the first time using the inexpensive NiCuMo/SiO2 catalyst to replace Ru-, Pt-, and Pd-containing catalysts in the process of reductive fractionation of abies wood into bioliquids and cellulose products. The optimal conditions of abies wood hydrogenation were selected to provide the effective depolymerization of wood lignin (250 °C, 3 h, initial H2 pressure 4 MPa). The composition and structure of the liquid and solid products of wood hydrogenation were established. The NiCuMo/SiO2 catalyst increases the yield of bioliquids (from 36 to 42 wt%) and the content of alkyl derivatives of methoxyphenols, predominantly 4-propylguaiacol and 4-propanolguaiacol. A decrease in the molecular mass and polydispersity (from 1870 and 3.01 to 1370 Da and 2.66, respectively) of the liquid products and a threefold increase (from 9.7 to 36.8 wt%) in the contents of monomer and dimer phenol compounds were observed in the presence of the catalyst. The solid product of catalytic hydrogenation of abies wood contains up to 73.2 wt% of cellulose. The composition and structure of the solid product were established using IRS, XRD, elemental and chemical analysis. The data obtained show that the catalyst NiCuMo/SiO2 can successfully replace noble metal catalysts in the process of abies wood reductive fractionation into bioliquids and cellulose.

Kuznetsov B.N. , Miroshnikova A.V. , Kazachenko A.S. , Baryshnikov S.V. , Malyar Y.N. , Yakovlev V.A. , Skripnikov A.M. , Fetisova O.Y. , Xu Y. , Taran O.P.
Reductive Catalytic Fractionation of Abies Wood into Bioliquids and Cellulose with Hydrogen in an Ethanol Medium over NiCuMo/SiO2 Catalyst
Catalysts. 2023. V.13. N2. 413 :1-19. DOI: 10.3390/catal13020413 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Dec 16, 2022
Accepted:	Feb 11, 2023
Published print:	Feb 15, 2023
Published online:	Feb 15, 2023

Web of science:	WOS:000938355700001
Scopus:	2-s2.0-85148959506
Elibrary:	50358014
Chemical Abstracts:	2023:433375
Chemical Abstracts (print):	182:128833
OpenAlex:	W4321097881

DB	Citing
Scopus	4
Web of science	4
Elibrary	5
OpenAlex	4