Co-Processing of Fossil Feedstock with Lignin-Derived Model Compound Isoeugenol over Fe-Ni/H-Y-5.1 Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Co-Processing of Fossil Feedstock with Lignin-Derived Model Compound Isoeugenol over Fe-Ni/H-Y-5.1 Catalysts Full article

Journal

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Output data

Year: 2023, Volume: 421, Pages: 101-116 Pages count : 16 DOI: 10.1016/j.jcat.2023.03.016

Tags

Co-processing; Bio-fuel; Lignin-derivative; Fe-Ni catalysts; Hydrodeoxygenation; Isoeugenol; Hexadecane

Authors

Vajglová Zuzana ¹ , Gauli Bibesh ¹ , Mäki-Arvela Päivi ¹ , Simakova Irina L. ² , Kumar Narendra ¹ , Eränen Kari ¹ , Tirri Teija ¹ , Lassfolk Robert ¹ , Peurla Markus ³ , Doronkin Dmitry E. ⁴ , Murzin Dmitry Yu. ¹

Affiliations

1	Åbo Akademi University, Johan Gadolin Process Chemistry Centre, Henriksgatan 2, 20500 Turku/Åbo, Finland
2	Boreskov Institute of Catalysis, Novosibirsk, Russia
3	Institute of Biomedicine, University of Turku, Kiinamyllynkatu 10, 20520 Turku, Finland
4	Institute of Chemical Technology and Polymer Chemistry, and Institute of Catalysis Research and Technology, Karlsruhe Institute of Technology, Kaiserstrasse 12, 76131 Karlsruhe, Germany

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	0239-2021-0008
2	Business Finland

Co-processing of n-hexadecane with lignin derived isoeugenol as a model compound was investigated in this work using low-cost mono- and bimetallic iron and nickel supported on H-Y-5.1 zeolite. Different FeNi metal ratios in the catalyst led to different reaction rates of processes and product distribution. The presence of just 0.26 wt% isoeugenol in the mixture with n-hexadecane made hydroisomerization-hydrocracking of the latter two-fold less active. Catalysts with smaller metal particle sizes, lower than 6 nm were more efficient pointing out on structure sensitivity. Extremely high activity in co-processing was obtained over 2 wt% Fe – 8 wt% Ni/H-Y-5.1 catalysts with the median metal particle size of 4.6 nm and metals-to-acid site ratio of 8.6. Fe catalyst were much less active in isoeugenol hydrodeoxygenation, while high cracking activity of hexadecane was observed in the presence of Ni. Alkylation of n-hexadecane was a feature of 8 wt% Fe – 2 wt% Ni/H-Y-5.1, whereas, over the 5 wt% Fe – 5 wt% Ni/H-Y5.1 bifunctional catalyst no undesired oxygen-containing cyclic products were detected. This catalyst exhibited the highest hydrogen consumption according to temperature programmed desorption, which can serve as a marker for efficient hydrodeoxygenation. The spent catalysts contained ca 40 wt% of coke with predominantly aliphatic species.

Vajglová Z. , Gauli B. , Mäki-Arvela P. , Simakova I.L. , Kumar N. , Eränen K. , Tirri T. , Lassfolk R. , Peurla M. , Doronkin D.E. , Murzin D.Y.
Co-Processing of Fossil Feedstock with Lignin-Derived Model Compound Isoeugenol over Fe-Ni/H-Y-5.1 Catalysts
Journal of Catalysis. 2023. V.421. P.101-116. DOI: 10.1016/j.jcat.2023.03.016 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Sep 21, 2022
Accepted:	Mar 6, 2023
Published online:	Mar 9, 2023
Published print:	May 1, 2023

Web of science:	WOS:000955293200001
Scopus:	2-s2.0-85150025632
Elibrary:	54082257
Chemical Abstracts:	2023:523166
OpenAlex:	W4323664593

DB	Citing
Scopus	12
Web of science	12
Elibrary	8
OpenAlex	11