Solution Combustion Synthesis of Ni/Al2O3 Catalyst for Methane Decomposition: Effect of Fuel | Sciact - CRIS-system of Boreskov Institute of Catalysis

Solution Combustion Synthesis of Ni/Al2O3 Catalyst for Methane Decomposition: Effect of Fuel Full article

Journal

Applied Sciences (Switzerland)
ISSN: 2076-3417

Output data

Year: 2023, Volume: 13, Number: 6, Article number : 3962, Pages count : 12 DOI: 10.3390/app13063962

Tags

methane; carbon nanofibers; hydrogen; solution combustion; fuel; carbon nanomaterials

Authors

Kurmashov Pavel B. ¹ , Ukhina Arina V. ² , Manakhov Anton ³ , Ishchenko Arkady V. ⁴ , Maksimovskii Evgenii A. ⁵ , Bannov Alexander G. ¹

Affiliations

1	Department of Chemistry and Chemical Engineering, Novosibirsk State Technical University, 630073 Novosibirsk, Russia
2	Institute of Chemistry of Solid State and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, 630092 Novosibirsk, Russia
3	Research Laboratory of Inorganic Nanomaterials, National University of Science and Technology (MISIS), Leniskiy Prospect, 4, 119049 Moscow, Russia
4	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia
5	Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

FSUN-2023-0008

The synthesis of a 90% Ni/Al2O3 catalyst via solution combustion synthesis with various fuels was studied in this work. Catalysts with a high content of the active component (i.e., nickel) were obtained as a result of the combustion of Ni(NO3)2·6H2O and Al(NO3)3·9H2O mixtures with fuel. The fuels, such as hexamethylenetetramine, glycine, urea, starch, citric acid, and oxalic acid, were investigated. The synthesis was carried out in a furnace, with the temperature being raised from room temperature to 450 °C at a rate of 1 °C per min. The paper evaluates the efficiency of fuels and their effect on the structure and properties of catalysts, as well as their catalytic activity. The catalyst was used for the synthesis of hydrogen and carbon nanofibers by methane decomposition at 1 bar and 550 °C. The catalysts were tested in a vertical flow reactor without preliminary reduction. The obtained samples of catalysts and carbon nanomaterials were studied by transmission electron microscopy, low-temperature nitrogen adsorption, and X-ray diffraction. The highest activity of the catalyst was obtained when citric acid was used as a fuel. The specific yields of hydrogen and carbon nanofibers were 17.1 mol/gcat and 171.3 g/gcat, respectively. Catalytic decomposition of methane led to the formation of cup-stacked carbon nanofibers.

Kurmashov P.B. , Ukhina A.V. , Manakhov A. , Ishchenko A.V. , Maksimovskii E.A. , Bannov A.G.
Solution Combustion Synthesis of Ni/Al2O3 Catalyst for Methane Decomposition: Effect of Fuel
Applied Sciences (Switzerland). 2023. V.13. N6. 3962 :1-12. DOI: 10.3390/app13063962 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Feb 25, 2023
Accepted:	Mar 14, 2023
Published print:	Mar 16, 2023
Published online:	Mar 20, 2023

Web of science:	WOS:000954642300001
Scopus:	2-s2.0-85152025069
Elibrary:	54908278
Chemical Abstracts:	2023:635770
OpenAlex:	W4328120749

DB	Citing
Web of science	3
Scopus	5
OpenAlex	5
Elibrary	6