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Spectral Characteristics of Ethylene Sorbed by Silver-Containing Ionic Liquids Studied by in situ ATR-FTIR Spectroscopy ArticleGenre_short.SHORT_COMMUNICATION

Journal Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X
Output data Year: 2023, Volume: 33, Number: 3, Pages: 425-427 Pages count : 3 DOI: 10.1016/j.mencom.2023.04.040
Tags ionic liquids, ethylene, silver, absorption, ATR-FTIR spectroscopy, π-complex
Authors Kovalev Evgeny P. 1 , Prikhod’ko Sergei A. 1 , Shalygin Anton S. 1 , Martyanov Oleg N. 1
Affiliations
1 G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0003

Abstract: The spectral characteristics of ethylene absorbed by ionic liquids (ILs) containing silver ions were studied by in situ ATR-FTIR spectroscopy at high pressure. Three different states of ethylene were observed based on the band shift of out-of-plane bending vibrations (wCH2) due to van der Waals interactions, hydrogen bonds, and p-complex formation with silver ions. Thus, ethylene can be used as an IR-sensitive probe molecule for characterizing interactions with ILs and other substances
Cite: Kovalev E.P. , Prikhod’ko S.A. , Shalygin A.S. , Martyanov O.N.
Spectral Characteristics of Ethylene Sorbed by Silver-Containing Ionic Liquids Studied by in situ ATR-FTIR Spectroscopy
Mendeleev Communications. 2023. V.33. N3. P.425-427. DOI: 10.1016/j.mencom.2023.04.040 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Jan 11, 2023
Published print: May 1, 2023
Published online: May 19, 2023
Identifiers:
Web of science: WOS:001018986900001
Scopus: 2-s2.0-85159594759
Elibrary: 53930190
Chemical Abstracts: 2023:1061558
OpenAlex: W4377046875
Citing:
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Scopus 4
Elibrary 2
OpenAlex 4
Web of science 4
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