Crystal Chemical Analysis of Two Modifications of [Pd(NH3)4]3Мо7O24·nH2O. Thermal Decomposition Products Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2023, Volume: 64, Number: 3, Pages: 450–461 Pages count : 12 DOI: 10.1134/s0022476623030101 | ||||
| Tags | palladium tetrammine, heptamolybdate anion, crystal modifications, single crystal X-ray diffraction analysis, thermal decomposition | ||||
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | FWUZ-2021-0005 (121031700313-8) |
Abstract:
A comparative crystal chemical analysis of о-[Pd(NH3)4]3Мо7O24·6H2O (а = 17.3472(3) Å, b = 28.9064(4) Å, с = 30.2463(4) Å, space group Ibca, V = 15166.9 Å3, Z = 16) and m-[Pd(NH3)4]3Мо7O24·3H2O (а = 10.6617(2) Å, b = 20.5248(5) Å,
с = 16.4676(3) Å, β = 103.0792(10)°, space group P21/n, V = 3510.11(13) Å3, Z = 4) is performed. Thermal decomposition products of o-[Pd(NH3)4]3Мо7O24·6H2O are studied. In the Н2 atmosphere at 900 °C, a mixture of mixed-metal solid solutions based on the Мо bcc lattice and the Pd fcc lattice is formed while in the 90% Не/10% Н2 atmosphere at 910 °C, a mixture of the solid solution based on the Мо bcc lattice and Pd2Mo3N is formed.
Cite:
Sukhikh A.S.
, Khranenko S.P.
, Zadesenets A.V.
, Gerasimov E.Y.
, Gromilov S.A.
Crystal Chemical Analysis of Two Modifications of [Pd(NH3)4]3Мо7O24·nH2O. Thermal Decomposition Products
Journal of Structural Chemistry. 2023. V.64. N3. P.450–461. DOI: 10.1134/s0022476623030101 WOS Scopus РИНЦ AN OpenAlex
Crystal Chemical Analysis of Two Modifications of [Pd(NH3)4]3Мо7O24·nH2O. Thermal Decomposition Products
Journal of Structural Chemistry. 2023. V.64. N3. P.450–461. DOI: 10.1134/s0022476623030101 WOS Scopus РИНЦ AN OpenAlex
Original:
Сухих А.С.
, Храненко С.П.
, Задесенец А.В.
, Герасимов Е.Ю.
, Громилов С.А.
Кристаллохимический анализ двух модификаций [Pd(NH3)4]3Мо7O24·nH2O. Продукты термического разложения
Журнал структурной химии. 2023. Т.64. №3. 107726 :1-13. DOI: 10.26902/jsc_id107726 РИНЦ OpenAlex
Кристаллохимический анализ двух модификаций [Pd(NH3)4]3Мо7O24·nH2O. Продукты термического разложения
Журнал структурной химии. 2023. Т.64. №3. 107726 :1-13. DOI: 10.26902/jsc_id107726 РИНЦ OpenAlex
Dates:
| Submitted: | Jan 24, 2023 |
| Accepted: | Feb 3, 2023 |
| Published print: | Mar 1, 2023 |
| Published online: | Apr 6, 2023 |
Identifiers:
| Web of science: | WOS:000964967500010 |
| Scopus: | 2-s2.0-85152655762 |
| Elibrary: | 54061365 |
| Chemical Abstracts: | 2023:719643 |
| OpenAlex: | W4362674541 |
Citing:
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