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Single-Atom Alloy Pd1Ag10/CeO2–ZrO2 as a Promising Catalyst for Selective Alkyne Hydrogenation Full article

Journal Inorganics
, E-ISSN: 2304-6740
Output data Year: 2023, Volume: 11, Number: 4, Article number : 150, Pages count : 13 DOI: 10.3390/inorganics11040150
Tags single-atom alloy catalyst; isolated Pd1 sites; liquid-phase hydrogenation; alkynes; diphenylacetylene; cerium–zirconium carrier; palladium–silver
Authors Markov Pavel V. 1 , Bragina Galina O. 1 , Smirnova Nadezhda S. 1 , Baeva Galina N. 1 , Mashkovsky Igor S. 1 , Gerasimov Evgeny Y. 2 , Bukhtiyarov Andrey V. 2 , Zubavichus Yan.V. 2 , Stakheev Alexander Y. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry RAS, Leninsky Prospect 47, 119991 Moscow, Russia
2 G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Academician Lavrentiev Prospect 5, 630090 Novosibirsk, Russia

Funding (1)

1 Russian Science Foundation 19-13-00285-П

Abstract: The effect of support on the performance of Pd1Ag10/Al2O3 and Pd1Ag10/CeO2–ZrO2 catalysts in the selective hydrogenation of diphenylacetylene (DPA) was studied. Characterization of the catalyst by DRIFTS-CO and HRTEM revealed the formation of a PdAg single-atom alloy (SAA) structure on the surface of PdAg nanoparticles, with Pd1 sites isolated by Ag atoms. It was found that the use of CeO2–ZrO2 as a carrier makes it possible to increase the activity of the Pd1Ag10 catalyst by a factor of three without loss of selectivity compared to the reference Pd1Ag10/Al2O3. According to the HRTEM data, this catalytic behavior can be explained by an increase in the dispersion of Pd1Ag10/CeO2–ZrO2 compared to its Pd1Ag10/Al2O3 counterpart. As evidenced by DRIFTS-CO data, the high selectivity of the Pd1Ag10/CeO2–ZrO2 sample presumably stems from the stability of the structure of isolated Pd1 sites on the surface of SAA Pd1Ag10/CeO2–ZrO2.
Cite: Markov P.V. , Bragina G.O. , Smirnova N.S. , Baeva G.N. , Mashkovsky I.S. , Gerasimov E.Y. , Bukhtiyarov A.V. , Zubavichus Y.V. , Stakheev A.Y.
Single-Atom Alloy Pd1Ag10/CeO2–ZrO2 as a Promising Catalyst for Selective Alkyne Hydrogenation
Inorganics. 2023. V.11. N4. 150 :1-13. DOI: 10.3390/inorganics11040150 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Mar 8, 2023
Accepted: Mar 29, 2023
Published print: Apr 1, 2023
Published online: Apr 1, 2023
Identifiers:
Web of science: WOS:000977511500001
Scopus: 2-s2.0-85153773971
Elibrary: 54146945
Chemical Abstracts: 2023:927570
OpenAlex: W4362586507
Citing:
DB Citing
Scopus 8
Web of science 8
Elibrary 10
OpenAlex 8
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