How Like-Charge Attraction Influences the Mobility of Cations in Hydroxyl-Functionalized Ionic Liquids | Sciact - CRIS-система Института катализа

How Like-Charge Attraction Influences the Mobility of Cations in Hydroxyl-Functionalized Ionic Liquids Научная публикация

Журнал

Journal of Physical Chemistry Letters
ISSN: 1948-7185

Вых. Данные

Год: 2023, Том: 14, Номер: 17, Страницы: 4019-4025 Страниц : 7 DOI: 10.1021/acs.jpclett.3c00463

Ключевые слова

Cations, Cluster chemistry, Liquids, Salts, Solvents

Авторы

Khudozhitkov Alexander E. ^1,5 , Paschek Dietmar ² , Stepanov Alexander G. ¹ , Kolokolov Daniil I. ^1,5 , Ludwig Ralf ^2,3,4

Организации

1	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2	Institut für Chemie, Abteilung für Physikalische Chemie, Universität Rostock, Albert-Einstein-Strasse 27, 18059 Rostock, Germany
3	Department LL&M, University of Rostock, Albert-Einstein-Strasse 25, 18059 Rostock, Germany
4	Leibniz-Institut für Katalyse an der Universität Rostock e.V., Albert-Einstein-Strasse 29a, 18059 Rostock, Germany
5	Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia

Информация о финансировании (5)

1	Российский научный фонд	21-13-00047
2	German Research Foundation	LU 506/15 (401427621)
3	German Research Foundation	LU 506/14-2 (286149019)
4	Alexander von Humboldt Foundation
5	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	0239-2021-0003

Attractive interactions between ions of like charge remain an elusive concept. Observing and quantifying this type of interaction in liquids and solutions is still a major challenge. Recently, we have shown that cation–cation interactions are present in hydroxyl-functionalized ionic liquids and that they can be controlled by the shape, charge distribution and functionality of the ions. In the present study, we demonstrate that cationic cluster formation does not only change the local structures of the ionic liquids but also influences the dynamics of the cations in a characteristic way. We show that solid-state 2H NMR spectroscopy is well suited for the study of molecular motion, even if the hydrogen bonded species of interest are indistinguishable due to fast deuteron exchange. We also provide valuable information about the applicability of well-accepted relaxation models.

Khudozhitkov A.E. , Paschek D. , Stepanov A.G. , Kolokolov D.I. , Ludwig R.
How Like-Charge Attraction Influences the Mobility of Cations in Hydroxyl-Functionalized Ionic Liquids
Journal of Physical Chemistry Letters. 2023. V.14. N17. P.4019-4025. DOI: 10.1021/acs.jpclett.3c00463 WOS Scopus РИНЦ CAPlus PMID OpenAlex

Поступила в редакцию:	17 февр. 2023 г.
Принята к публикации:	31 мар. 2023 г.
Опубликована online:	24 апр. 2023 г.
Опубликована в печати:	4 мая 2023 г.

Web of science:	WOS:000982236300001
Scopus:	2-s2.0-85156199106
РИНЦ:	54061458
Chemical Abstracts:	2023:822929
PMID (PubMed):	37093004
OpenAlex:	W4366821937

БД	Цитирований
Scopus	3
Web of science	1
РИНЦ	2
OpenAlex	3