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Template Synthesis of B-Doped Graphene-Like Carbon Nanomaterial from Phenylboronic Acid Full article

Journal Fullerenes Nanotubes and Carbon Nanostructures
ISSN: 1536-383X , E-ISSN: 1536-4046
Output data Year: 2023, Volume: 31, Number: 8, Pages: 796-803 Pages count : 8 DOI: 10.1080/1536383x.2023.2209227
Tags Graphene, magnesium oxide, phenylboronic acid, carbonization
Authors Chesnokov Vladimir V. 1 , Paukshtis Evgeniy A. 1 , Prosvirin Igor P. 1 , Gerasimov Evgeny Y. 1
Affiliations
1 Boreskov Institute of Catalysis, SB RAS Prospekt Akademika Lavrentieva 5, Novosibirsk, Russia

Funding (1)

1 Russian Science Foundation 17-73-30032

Abstract: A template method for synthesis of B-doped graphene-like carbon nanomaterial (B-graphene-like carbon) with high surface area has been developed. In this method, magnesium oxide is used as a template where a carbon layer doped with boron atoms is deposited. Magnesium oxide carbonization was performed in an autoclave at 600 °C and 5 atm pressure using phenylboronic acid (FBA) dissolved in an ethanol-acetone mixture. Then, magnesium oxide from the С—B/MgO composite was dissolved in hydrochloric acid. The obtained B- graphene-like carbon was studied by IR spectroscopy, electron microscopy, XPS methods and quantum chemical calculations. B-graphene-like carbon contains 3–6 carbon layers and 0.2 wt% B. Structure of carbon net with embedded boron fragment has been proposed as the result of performed studies.
Cite: Chesnokov V.V. , Paukshtis E.A. , Prosvirin I.P. , Gerasimov E.Y.
Template Synthesis of B-Doped Graphene-Like Carbon Nanomaterial from Phenylboronic Acid
Fullerenes Nanotubes and Carbon Nanostructures. 2023. V.31. N8. P.796-803. DOI: 10.1080/1536383x.2023.2209227 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Mar 2, 2023
Accepted: Apr 26, 2023
Published online: May 9, 2023
Published print: Aug 1, 2023
Identifiers:
Web of science: WOS:000983650600001
Scopus: 2-s2.0-85158965216
Elibrary: 54387560
Chemical Abstracts: 2023:985218
OpenAlex: W4376107583
Citing:
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Scopus 2
Web of science 2
OpenAlex 2
Elibrary 1
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