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Activation of the Combustion of Low-Reactivity Solid Fuels with Metal-Rolling Production Waste Full article

Journal Energy
ISSN: 0360-5442 , E-ISSN: 1873-6785
Output data Year: 2023, Volume: 278, Number: Part B, Article number : 128009, Pages count : 12 DOI: 10.1016/j.energy.2023.128009
Tags anthracite, semi-coke, metal scale, oxidation, combustion, activation
Authors Larionov K.B. 1,2 , Mishakov I.V. 3 , Gorshkov A.S. 1,2 , Kaltaev A.Zh. 1 , Asilbekov A.K. 1 , Gubin A.V. 1 , Slyusarsky K.V. 1,2 , Gerasimov R.D. 1 , Vedyagin A.A. 3
Affiliations
1 National Research Tomsk Polytechnic University, Tomsk, 634050, Russia
2 Gorbachev Kuzbass State Technical University, Kemerovo, 650000, Russia
3 Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia

Funding (1)

1 Russian Science Foundation 21-79-00091 (121081800047-6)

Abstract: The effect of the addition of different amounts of metal-rolling production waste (metal scale in amount of 1–10 wt%) on combustion characteristics of low-reactive solid fuels (anthracite and semi-coke) was studied. XRD analysis of the metal scale identified Fe3O4 and Mn3O4 phases along with a cubic Fe phase. The characteristics of ignition and combustion of the samples were studied via thermal analysis and high-speed video recording at heating medium temperatures of 600–800 °C (with 100 °C step) using a combustion chamber. It was experimentally found that the addition of a metal scale, regardless of its weight content, increases the fuel reactivity, as evidenced by the drop in temperature of the onset of intense oxidation (ΔTi) by 2–32 °C and the decrease in the ignition delay time (Δτi) by 0.2–2.2 s. The metal scale additive also increases the fuel combustion rate, which was evidenced by the maximum rate of oxidation (Δwmax) increasing by 0.1–2.0 wt%/min and, hence, the temperature of the end of oxidation (ΔTf) reducing by 13–68 °C. Due to combustion intensification, the carbon content in ash decreased by 55 rel% on average. The amount of CO and NOx contained in gas-phase combustion products diminished as well.
Cite: Larionov K.B. , Mishakov I.V. , Gorshkov A.S. , Kaltaev A.Z. , Asilbekov A.K. , Gubin A.V. , Slyusarsky K.V. , Gerasimov R.D. , Vedyagin A.A.
Activation of the Combustion of Low-Reactivity Solid Fuels with Metal-Rolling Production Waste
Energy. 2023. V.278. NPart B. 128009 :1-12. DOI: 10.1016/j.energy.2023.128009 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Dec 4, 2022
Accepted: Jun 1, 2023
Published online: Jun 2, 2023
Published print: Sep 1, 2023
Identifiers:
Web of science: WOS:001018143300001
Scopus: 2-s2.0-85161341052
Elibrary: 55988486
Chemical Abstracts: 2023:1265471
Chemical Abstracts (print): 183:179790
OpenAlex: W4379144987
Citing:
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Scopus 4
OpenAlex 4
Elibrary 3
Web of science 4
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