L-Cysteine Nitrates | Sciact - CRIS-system of Boreskov Institute of Catalysis

L-Cysteine Nitrates Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2023, Volume: 64, Number: 5, Pages: 917-931 Pages count : 15 DOI: 10.1134/s0022476623050104

Tags

L-cysteine, nitrates, crystal structure, dimeric cation, vibrational spectra, short hydrogen bonds

Authors

Giester G. ¹ , Ghazaryan V.V. ² , Minkov V.S. ³ , Boldyreva E.V. ^4,5 , Petrosyan A.M. ²

Affiliations

1	Institute of Mineralogy and Crystallography, University of Vienna, Vienna, Austria
2	Institute of Applied Problems of Physics, National Academy of Sciences of Armenia, Yerevan, Armenia
3	Max-Planck Institut für Chemie, Mainz, Germany
4	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
5	Novosibirsk State University, Novosibirsk, Russia

Funding (2)

1	Armenian National Science & Education Fund	matsc-3822
2	Russian Foundation for Basic Research	15-53-05023 (115042410027)

The formation of salts in the L-cysteine–HNO3–H2O system was studied yielding three representatives as single crystals: anhydrous L-cysteinium nitrate (L-CysH)NO3 (I) and two new salts (L-CysH⋯L-Cys)NO3 (II) and (L-CysH⋯L-Cys)NO3∙0.5H2O (III) with the dimeric (L-CysH⋯L-Cys) cation. (I), (II) and (III) crystallize in space groups P212121, P21 and I2, respectively. Dimeric cations in (II) and (III) were formed by very short O–H⋯O hydrogen bonds with R(O⋯O) distances of 2.440(2) Å and 2.4352(17) Å, respectively. Infrared and Raman spectra of (I–III) were registered and discussed in relation to crystal structures. Characteristics of dimeric cations are compared with those in the previously obtained compounds of L-CysH(L-CysH⋯L-Cys)F(F⋯HF), (L-CysH⋯L-Cys)Cl, (L-CysH⋯L-Cys)Br and (L-CysH⋯L-Cys)I·0.5H2O.

Giester G. , Ghazaryan V.V. , Minkov V.S. , Boldyreva E.V. , Petrosyan A.M.
L-Cysteine Nitrates
Journal of Structural Chemistry. 2023. V.64. N5. P.917-931. DOI: 10.1134/s0022476623050104 WOS Scopus РИНЦ OpenAlex AN

Giester G. , Ghazaryan V.V. , Minkov V.S. , Boldyreva E.V. , Petrosyan A.M.
L-Cysteine Nitrates
Журнал структурной химии. 2023. V.64. N5. 111045 :1-3. DOI: 10.26902/jsc_id111045 РИНЦ OpenAlex

Submitted:	Apr 4, 2023
Accepted:	Apr 11, 2023
Published print:	May 30, 2023
Published online:	May 30, 2023

≡ Web of science:	WOS:000999902000010
≡ Scopus:	2-s2.0-85160930687
≡ Elibrary:	54385577
≡ OpenAlex:	W4381294714
≡ Chemical Abstracts:	2023:1143550

≡ Scopus	3	Сбор данных от 15.02.2026
≡ Web of science	3	Сбор данных от 20.02.2026
≡ OpenAlex	3	Сбор данных от 15.02.2026
≡ Elibrary	4	Сбор данных от 15.02.2026