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Studying Effects of External Conditions of Electrochemical Measurements on the Photoelectrochemical Properties of Semiconductors: Cyclic Voltammetry, Impedance Spectroscopy, and Mott – Schottky Method Full article

Journal Electrochemical Materials and Technologies
, E-ISSN: 2949-0561
Output data Year: 2023, Volume: 2, Number: 2, Article number : 20232013, Pages count : 14 DOI: 10.15826/elmattech.2023.2.013
Tags electrochemical methods; impedance; external voltage; amplitude; Mott – Schottky plot; cyclic voltammetry
Authors Markovskaya Dina 1 , Sidorenko Nikolay 1 , Zhurenok Angelina 1 , Kozlova Ekaterina 1
Affiliations
1 Department of heterogeneous catalysis, Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Funding (1)

1 Russian Science Foundation 21-13-00314

Abstract: In this paper, the dependences of the semiconductors’ photoelectrochemical properties on the experimental conditions were studied for the solid solution of CdS and ZnS, graphitic carbon nitride, and the platinized carbon nitride. The cyclic voltammograms were obtained under different scan rates. The sample investigations were carried out by two ways, at the constant external voltage and varied amplitudes and at different external voltages and the fixed amplitude. The Mott – Schottky dependences were studied at different frequencies. The basic dependences of the changes in the photoelectrode target characteristics on the experimental condition were found. Some recommendations for the correct comparison of qualitative and quantitative photoelectrochemical data were formulated.
Cite: Markovskaya D. , Sidorenko N. , Zhurenok A. , Kozlova E.
Studying Effects of External Conditions of Electrochemical Measurements on the Photoelectrochemical Properties of Semiconductors: Cyclic Voltammetry, Impedance Spectroscopy, and Mott – Schottky Method
Electrochemical Materials and Technologies. 2023. V.2. N2. 20232013 :1-14. DOI: 10.15826/elmattech.2023.2.013 РИНЦ OpenAlex
Dates:
Submitted: May 3, 2023
Accepted: Jun 1, 2023
Published online: Jun 9, 2023
Identifiers:
Elibrary: 54492687
OpenAlex: W4380631382
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