Catalytic Methods for Producing Higher 2-Ketones: Prospects for the Wacker System in the Oxidation of α-Olefins (A Review) Review
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2023, Volume: 64, Number: 2, Pages: 105–121 Pages count : 17 DOI: 10.1134/S0023158423020064 | ||
| Tags | metal complex catalysis, Wacker oxidation, α-olefins, 2-ketones, Pd-containing catalytic systems | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0005 |
Abstract:
Methods developed over the past 60 years for the preparation of unbranched С6–С14 2-ketones by catalytic oxidation of linear α-olefins have been analyzed and summarized. Particular attention has been paid to the consideration of the catalytic Wacker system, which is important for industrial organic synthesis, and the proposed ways for its modification. Methods for controlling the reaction selectivity have been discussed, and the role of cocatalysts, oxidizing agents, and ligands has been considered.
Cite:
Rodikova Y.A.
, Zhizhina E.G.
Catalytic Methods for Producing Higher 2-Ketones: Prospects for the Wacker System in the Oxidation of α-Olefins (A Review)
Kinetics and Catalysis. 2023. V.64. N2. P.105–121. DOI: 10.1134/S0023158423020064 WOS Scopus РИНЦ ANCAN OpenAlex
Catalytic Methods for Producing Higher 2-Ketones: Prospects for the Wacker System in the Oxidation of α-Olefins (A Review)
Kinetics and Catalysis. 2023. V.64. N2. P.105–121. DOI: 10.1134/S0023158423020064 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Родикова Ю.А.
, Жижина Е.Г.
Каталитические методы получения высших 2-кетонов: перспективы вакер-системы в реакции окисления α-олефинов
Кинетика и катализ. 2023. Т.64. №2. С.121-138. DOI: 10.31857/S0453881123020065 РИНЦ OpenAlex
Каталитические методы получения высших 2-кетонов: перспективы вакер-системы в реакции окисления α-олефинов
Кинетика и катализ. 2023. Т.64. №2. С.121-138. DOI: 10.31857/S0453881123020065 РИНЦ OpenAlex
Dates:
| Submitted: | Sep 26, 2022 |
| Accepted: | Dec 2, 2022 |
| Published print: | Apr 1, 2023 |
| Published online: | Jun 16, 2023 |
Identifiers:
| Web of science: | WOS:001011416800001 |
| Scopus: | 2-s2.0-85161963231 |
| Elibrary: | 54061148 |
| Chemical Abstracts: | 2023:1256893 |
| Chemical Abstracts (print): | 183:226019 |
| OpenAlex: | W4380760370 |