Kinetics of the Catalytic Oxidation of Methyl Oleate Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2023, Volume: 64, Number: 3, Pages: 270–275 Pages count : 6 DOI: 10.1134/S0023158423030102 | ||
| Tags | oleic acid, methyl oleate, epoxides, tungsten peroxo complexes, hydrogen peroxide, homogeneous and heterogeneous catalysis | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0005 |
Abstract:
The results of studying the reaction kinetics of the catalytic oxidation of methyl oleate with hydrogen peroxide in a two-phase system (aqueous phase-organic phase) in the presence of the bifunctional catalyst [(Octn)3NMe]3{PO4[WO(O2)2]4} are presented. For the selected reaction conditions, the first orders of reaction with respect to the catalyst, substrate, and oxidizing agent were established. The activation energy was 47 ± 3 kJ/mol in a temperature range of 313–353 K, and the preexponential factor was (6.0 ± 0.3) × 107 L2 mol–2 min–1.
Cite:
Yushchenko D.Y.
, Pai Z.P.
, Uchenova Y.V.
, Khlebnikova T.B.
Kinetics of the Catalytic Oxidation of Methyl Oleate
Kinetics and Catalysis. 2023. V.64. N3. P.270–275. DOI: 10.1134/S0023158423030102 WOS Scopus РИНЦ AN OpenAlex
Kinetics of the Catalytic Oxidation of Methyl Oleate
Kinetics and Catalysis. 2023. V.64. N3. P.270–275. DOI: 10.1134/S0023158423030102 WOS Scopus РИНЦ AN OpenAlex
Original:
Ющенко Д.Ю.
, Пай З.П.
, Ученова Ю.В.
, Хлебникова Т.Б.
Кинетика каталитического окисления метилового эфира олеиновой кислоты
Кинетика и катализ. 2023. Т.64. №3. С.298-304. DOI: 10.31857/S0453881123030127 РИНЦ OpenAlex
Кинетика каталитического окисления метилового эфира олеиновой кислоты
Кинетика и катализ. 2023. Т.64. №3. С.298-304. DOI: 10.31857/S0453881123030127 РИНЦ OpenAlex
Dates:
| Submitted: | Dec 26, 2022 |
| Accepted: | Feb 2, 2023 |
| Published print: | Jun 23, 2023 |
| Published online: | Jun 23, 2023 |
Identifiers:
| Web of science: | WOS:001013206900006 |
| Scopus: | 2-s2.0-85162955705 |
| Elibrary: | 54061264 |
| Chemical Abstracts: | 2023:1309161 |
| OpenAlex: | W4381734595 |