Features of Cl K-edge XANES Spectra of Transition Metal Complexes {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt) | Sciact - CRIS-system of Boreskov Institute of Catalysis

Features of Cl K-edge XANES Spectra of Transition Metal Complexes {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt) Full article

Journal

Bulletin of the Russian Academy of Sciences: Physics
ISSN: 1062-8738 , E-ISSN: 1934-9432

Output data

Year: 2023, Volume: 87, Number: 5, Pages: 654-661 Pages count : 8 DOI: 10.3103/s1062873822701805

Tags

Chlorine; Chlorine compounds; Metal complexes; Transition metal compounds

Authors

Fedorenko A.D. ¹ , Asanov I.P. ¹ , Asanova T.I. ¹ , Vasil’chenko D.B. ¹ , Nikolenko A.D. ^2,3,4 , Piminov P.A. ^3,4 , Karyukina K.Yu. ^3,4

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
3	Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
4	SKIF Synchrotron Radiation Facility, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Koltsovo, 630559 Russia

Funding (1)

Russian Science Foundation

22-22-00683

Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes.

Fedorenko A.D. , Asanov I.P. , Asanova T.I. , Vasil’chenko D.B. , Nikolenko A.D. , Piminov P.A. , Karyukina K.Y.
Features of Cl K-edge XANES Spectra of Transition Metal Complexes {MCl6}n− (M = Rh, Pd, Re, Os, Ir, Pt)
Bulletin of the Russian Academy of Sciences: Physics. 2023. V.87. N5. P.654-661. DOI: 10.3103/s1062873822701805 Scopus РИНЦ AN OpenAlex

Федоренко А.Д. , Асанов И.П. , Асанова Т.И. , Васильченко Д.Б. , Николенко А.Д. , Пиминов П.А. , Карюкина К.Ю.
Особенности XANES спектров вблизи Cl K-края в комплексах переходных металлов {MCl6}N– (M = Rh, Pd, Re, Os, Ir, Pt)
Известия Российской академии наук. Серия физическая. 2023. Т.87. №5. С.738-746. DOI: 10.31857/S0367676522701253 РИНЦ OpenAlex

Submitted:	Nov 28, 2022
Accepted:	Jan 25, 2023
Published print:	May 1, 2023
Published online:	Jun 16, 2023

Scopus:	2-s2.0-85161989931
Elibrary:	54251804
Chemical Abstracts:	2023:1257187
OpenAlex:	W4380874989

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