Photocatalysts Based on Graphite-like Carbon Nitride with a Low Content of Rhodium and Palladium for Hydrogen Production under Visible Light Научная публикация
| Журнал |
Nanomaterials
, E-ISSN: 2079-4991 |
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| Вых. Данные | Год: 2023, Том: 13, Номер: 15, Номер статьи : 2176, Страниц : 16 DOI: 10.3390/nano13152176 | ||||
| Ключевые слова | photocatalysis; hydrogen evolution; g-C3N4; noble metals; rhodium; palladium | ||||
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| Организации |
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Информация о финансировании (1)
| 1 | Российский научный фонд | 21-13-00314 |
Реферат:
In this study, we proposed photocatalysts based on graphite-like carbon nitride with a low content (0.01–0.5 wt.%) of noble metals (Pd, Rh) for hydrogen evolution under visible light irradiation. As precursors of rhodium and palladium, labile aqua and nitrato complexes [Rh2(H2O)8(μ-OH)2](NO3)4∙4H2O and (Et4N)2[Pd(NO3)4], respectively, were proposed. To obtain metallic particles, reduction was carried out in H2 at 400 °C. The synthesized photocatalysts were studied using X-ray diffraction, X-ray photoelectron spectroscopy, UV–Vis diffuse reflectance spectroscopy and high-resolution transmission electron microscopy. The activity of the photocatalysts was tested in the hydrogen evolution from aqueous and aqueous alkaline solutions of TEOA under visible light with a wavelength of 428 nm. It was shown that the activity for the 0.01–0.5% Rh/g-C3N4 series is higher than in the case of the 0.01–0.5% Pd/g-C3N4 photocatalysts. The 0.5% Rh/g-C3N4 sample showed the highest activity per gram of catalyst, equal to 3.9 mmol gcat–1 h–1, whereas the most efficient use of the metal particles was found over the 0.1% Rh/g-C3N4 photocatalyst, with the activity of 2.4 mol per gram of Rh per hour. The data obtained are of interest and can serve for further research in the field of photocatalytic hydrogen evolution using noble metals as cocatalysts.
Библиографическая ссылка:
Zhurenok A.V.
, Vasichenko D.B.
, Berdyugin S.N.
, Gerasimov E.Y.
, Saraev A.A.
, Cherepanova S.V.
, Kozlova E.A.
Photocatalysts Based on Graphite-like Carbon Nitride with a Low Content of Rhodium and Palladium for Hydrogen Production under Visible Light
Nanomaterials. 2023. V.13. N15. 2176 :1-16. DOI: 10.3390/nano13152176 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Photocatalysts Based on Graphite-like Carbon Nitride with a Low Content of Rhodium and Palladium for Hydrogen Production under Visible Light
Nanomaterials. 2023. V.13. N15. 2176 :1-16. DOI: 10.3390/nano13152176 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
| Поступила в редакцию: | 1 июл. 2023 г. |
| Принята к публикации: | 24 июл. 2023 г. |
| Опубликована online: | 26 июл. 2023 г. |
| Опубликована в печати: | 1 авг. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:001045570300001 |
| Scopus: | 2-s2.0-85167730554 |
| РИНЦ: | 54378126 |
| Chemical Abstracts: | 2023:1716837 |
| PMID (PubMed): | 37570494 |
| OpenAlex: | W4385308347 |