Synthesis, X-ray Structure and Magnetic Properties of the Apically Functionalized Monocapped Cobalt(ii) tris-Pyridineoximates Possessing SMM Behaviour | Sciact - CRIS-система Института катализа

Synthesis, X-ray Structure and Magnetic Properties of the Apically Functionalized Monocapped Cobalt(ii) tris-Pyridineoximates Possessing SMM Behaviour Научная публикация

Журнал

Dalton Transactions
ISSN: 1477-9226 , E-ISSN: 1477-9234

Вых. Данные

Год: 2023, Том: 52, Номер: 10, Страницы: 2928-2932 Страниц : 5 DOI: 10.1039/d2dt04073e

Авторы

Belov Alexander S. ^1,2 , Belova Svetlana A. ^1,2 , Efimov N.N. ¹ , Zlobina Veronika V. ² , Novikov Valentin V. ^3,4 , Nelyubina Yulia V. ^2,4 , Zubavichus Yan V. ⁵ , Voloshin Yan Z. ^1,2 , Pavlov A.A. ^2,3,6

Организации

1	Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 31 Leninsky pr., 119991 Moscow, Russia
2	Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 28-1 Vavilova st., 119334 Moscow, Russia
3	Moscow Institute of Physics and Technology, National Research University, Institutsliy per. 9, Dolgoprudny, 141700 Moscow Region, Russia
4	BMSTU Center of National Technological Initiative “Digital Material Science: New Material and Substances”, Bauman Moscow State Technical University, 2nd Baumanskaya st. 5, Moscow, Russia
5	Synchrotron Radiation Facility SKIF, G.K. Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences, 1 Nikolskii pr., 630559 Koltsovo, Russia
6	National Research University Higher School of Economics, 101000 Moscow, Russia

The title cobalt(II) pseudoclathrochelate complexes possess an intermediate trigonal prismatic–trigonal antiprismatic geometry. As follows from PPMS data, they exhibit an SMM behaviour with Orbach relaxation barriers of approximately 90 K. Paramagnetic NMR experiments confirmed a persistence of these magnetic characteristics in solution. Therefore, a straightforward apical functionalization of this 3D molecular platform for its targeted delivery to a given biosystem can be performed without substantial changes.

Belov A.S. , Belova S.A. , Efimov N.N. , Zlobina V.V. , Novikov V.V. , Nelyubina Y.V. , Zubavichus Y.V. , Voloshin Y.Z. , Pavlov A.A.
Synthesis, X-ray Structure and Magnetic Properties of the Apically Functionalized Monocapped Cobalt(ii) tris-Pyridineoximates Possessing SMM Behaviour
Dalton Transactions. 2023. V.52. N10. P.2928-2932. DOI: 10.1039/d2dt04073e WOS Scopus РИНЦ OpenAlex CAPlusCA PMID СКИФ ID

Поступила в редакцию:	20 дек. 2022 г.
Принята к публикации:	7 февр. 2023 г.
Опубликована online:	7 февр. 2023 г.
Опубликована в печати:	1 мар. 2023 г.

≡ Web of science:	WOS:000936294100001
≡ Scopus:	2-s2.0-85150000129
≡ РИНЦ:	60441312
≡ OpenAlex:	W4319437427
≡ Chemical Abstracts:	2023:363534
≡ Chemical Abstracts (print):	182:180160
≡ PMID (PubMed):	36811361
≡ СКИФ ID:	580

≡ OpenAlex	13	Сбор данных от 15.02.2026
≡ Web of science	14	Сбор данных от 13.02.2026
≡ Scopus	13	Сбор данных от 15.02.2026