Dry Reforming of Methane over Ni–Fe–Al Catalysts Prepared by Solution Combustion Synthesis | Sciact - CRIS-система Института катализа

Dry Reforming of Methane over Ni–Fe–Al Catalysts Prepared by Solution Combustion Synthesis Научная публикация

Журнал

Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045

Вых. Данные

Год: 2023, Том: 62, Номер: 29, Страницы: 11439-11455 Страниц : 17 DOI: 10.1021/acs.iecr.3c00272

Ключевые слова

Alloys, Catalysts, Diffraction, Oxides, Particle size

Авторы

Manabayeva Alua M. ^1,2,3 , Mäki-Arvela Päivi ² , Vajglová Zuzana ² , Martinéz-Klimov Mark ² , Tirri Teija ² , Baizhumanova Tolkyn S. ^3,4 , Grigor’eva Valentina P. ³ , Zhumabek Manapkhan ³ , Aubakirov Yermek A. ⁴ , Simakova Irina L. ⁵ , Murzin Dmitry Yu. ² , Tungatarova Svetlana A. ^3,4

Организации

1	Kazakh-British Technical University, Almaty 050000, Kazakhstan
2	Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, Turku 20500, Finland
3	D.V. Sokolsky Institute of Fuel, Catalysis and Electrochemistry, Almaty 050000, Kazakhstan
4	Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan
5	Boreskov Institute of Catalysis, Novosibirsk 630090, Russia

Информация о финансировании (1)

Министерство науки и высшего образования Республики Казахстан

AP14869966

Dry reforming of methane (DRM) is a promising method to utilize two greenhouse gases, such as CH4 and CO2, to produce synthesis gas. In the current work, both monometallic Ni and bimetallic Ni–Fe catalysts with different Fe/Ni molar ratios, synthesized by solution combustion synthesis (SCS) in DRM, were investigated using a feed ratio of CH4/CO2/Ar of 1:1:1 at 600–900 °C. The catalysts were characterized by several physicochemical techniques such as X-ray diffraction (XRD), scanning electron microscopy energy-dispersive X-ray (SEM-EDX) spectroscopy, transmission electron microscopy (TEM), CHNS, N2 physisorption, H2-TPR, O2-TPO, NH3-TPD, and thermogravimetric analysis (TGA). One of the highest hydrogen yields of 81% was obtained at 93% conversion of CH4 and 94% conversion of CO2 for the bimetallic 15Ni–5Fe–30Al catalyst, which contained, according to XRD, NiAl2O4 spinel and metallic Ni phases. The spinel phase was decomposed during the reaction, while the Ni3Fe alloy was formed. Catalysts with a higher Fe/Ni ratio exhibited lower conversion and contained an inactive FeAl2O4 spinel. Rather stable yields of CO and H2 were obtained in an experiment with 20 h time-on-stream.

Manabayeva A.M. , Mäki-Arvela P. , Vajglová Z. , Martinéz-Klimov M. , Tirri T. , Baizhumanova T.S. , Grigor’eva V.P. , Zhumabek M. , Aubakirov Y.A. , Simakova I.L. , Murzin D.Y. , Tungatarova S.A.
Dry Reforming of Methane over Ni–Fe–Al Catalysts Prepared by Solution Combustion Synthesis
Industrial and Engineering Chemistry Research. 2023. V.62. N29. P.11439-11455. DOI: 10.1021/acs.iecr.3c00272 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	30 янв. 2023 г.
Принята к публикации:	30 июн. 2023 г.
Опубликована online:	18 июл. 2023 г.
Опубликована в печати:	26 июл. 2023 г.

Web of science:	WOS:001031292300001
Scopus:	2-s2.0-85166595077
РИНЦ:	54372679
Chemical Abstracts:	2023:1469911
OpenAlex:	W4384698395

БД	Цитирований
Scopus	10
OpenAlex	15
Web of science	11
РИНЦ	10