Catalysts for Liquid-Phase Oxidation of Organic Compounds with Hydrogen Peroxide: Homogeneous and Phase Transfer Systems Review
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2023, Volume: 64, Number: 4, Pages: 329–361 Pages count : 33 DOI: 10.1134/s0023158423040110 | ||
| Tags | oxo- and peroxopolyoxometalates; quaternary ammonium cations; EXAFS; SAXS; NMR; Raman and IR spectroscopy; homogeneous and phase-transfer catalysis; liquid-phase oxidation of organic compounds; hydrogen peroxide | ||
| Authors |
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| Affiliations |
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Funding (12)
| 1 | Russian Foundation for Basic Research | 01-03-32862 |
| 2 | Russian Foundation for Basic Research | 04-03-32425 |
| 3 | Russian Foundation for Basic Research | 09-03-00395 |
| 4 | Russian Foundation for Basic Research | 12-03-00173 |
| 5 | Russian Foundation for Basic Research | 16-03-00127 |
| 6 | Russian Foundation for Basic Research | 16-29-10691 |
| 7 | Russian Foundation for Basic Research | 19-03-00202 |
| 8 | Federal Agency for Scientific Organizations | V.44.2.8. |
| 9 | Президиум РАН | 4.6.3 |
| 10 | Президиум РАН | 5.7.3 |
| 11 | Ministry of Science and Higher Education of the Russian Federation | 0239-2021-0005 |
| 12 | Federal Agency for Scientific Organizations | 0303-2016-0008 |
Abstract:
The review presents a comparative analysis of promising homogeneous metal complex catalysts and the results of studies on the synthesis and determination of the structural characteristics of efficient catalysts for the oxidation of organic compounds with hydrogen peroxide Q3{PO4[WO(O2)2]4} (Q is the quaternary ammonium cation) by EXAFS, SAXS, NMR, Raman, and IR spectroscopy. The possibilities of using bifunctional homogeneous peroxopolyoxo metal complexes in combination with organic cations having quaternized nitrogen under conditions of phase transfer catalysis were considered using as an example the oxidation of organic compounds of various classes with hydrogen peroxide, forming aliphatic and aromatic epoxides, mono- and dicarboxylic acids, as well as biologically active compounds for medical and agroindustrial purposes.
Cite:
Pai Z.P.
, Parmon V.N.
, Bukhtiyarov V.I.
Catalysts for Liquid-Phase Oxidation of Organic Compounds with Hydrogen Peroxide: Homogeneous and Phase Transfer Systems
Kinetics and Catalysis. 2023. V.64. N4. P.329–361. DOI: 10.1134/s0023158423040110 WOS Scopus РИНЦ AN OpenAlex
Catalysts for Liquid-Phase Oxidation of Organic Compounds with Hydrogen Peroxide: Homogeneous and Phase Transfer Systems
Kinetics and Catalysis. 2023. V.64. N4. P.329–361. DOI: 10.1134/s0023158423040110 WOS Scopus РИНЦ AN OpenAlex
Original:
Пай З.П.
, Пармон В.Н.
, Бухтияров В.И.
Катализаторы жидкофазного окисления пероксидом водорода органических соединений: гомогенные и межфазные системы
Кинетика и катализ. 2023. Т.64. №4. С.347-383. DOI: 10.31857/S0453881123040123 РИНЦ OpenAlex
Катализаторы жидкофазного окисления пероксидом водорода органических соединений: гомогенные и межфазные системы
Кинетика и катализ. 2023. Т.64. №4. С.347-383. DOI: 10.31857/S0453881123040123 РИНЦ OpenAlex
Dates:
| Submitted: | Feb 2, 2023 |
| Accepted: | Mar 21, 2023 |
| Published online: | Jul 23, 2023 |
| Published print: | Aug 1, 2023 |
Identifiers:
| Web of science: | WOS:001034791000001 |
| Scopus: | 2-s2.0-85165602907 |
| Elibrary: | 54369234 |
| Chemical Abstracts: | 2023:1546927 |
| OpenAlex: | W4385155811 |