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Design of Mixed Ionic-Electronic Materials for Permselective Membranes and Solid Oxide Fuel Cells Based on Their Oxygen and Hydrogen Mobility Review

Journal Membranes
ISSN: 2077-0375
Output data Year: 2023, Volume: 13, Number: 8, Article number : 698, Pages count : 53 DOI: 10.3390/membranes13080698
Tags solid oxide fuel cells; oxygen separation membranes; hydrogen separation membranes; oxygen mobility; hydrogen mobility; isotope exchange of oxygen
Authors Sadykov V. 1 , Pikalova E. 2,3 , Sadovskaya E. 1 , Shlyakhtina A. 4 , Filonova E. 5 , Eremeev N. 1
Affiliations
1 Federal Research Center, Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
2 Institute of High Temperature Electrochemistry UB RAS, 620137 Yekaterinburg, Russia
3 Graduate School of Economics and Management, Ural Federal University, 620002 Yekaterinburg, Russia
4 Federal Research Center, Semenov Institute of Chemical Physics RAS, 119991 Moscow, Russia
5 Institute of Natural Sciences and Mathematics, Ural Federal University, 620002 Yekaterinburg, Russia

Funding (4)

1 Russian Science Foundation 23-73-00045
2 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0005
3 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0011
4 Ministry of Science and Higher Education of the Russian Federation 075-03-2022-351 (122020100324-3) (FUME-2022-0006)

Abstract: Oxygen and hydrogen mobility are among the important characteristics for the operation of solid oxide fuel cells, permselective membranes and many other electrochemical devices. This, along with other characteristics, enables a high-power density in solid oxide fuel cells due to reducing the electrolyte resistance and enabling the electrode processes to not be limited by the electrode-electrolyte-gas phase triple-phase boundary, as well as providing high oxygen or hydrogen permeation fluxes for membranes due to a high ambipolar conductivity. This work focuses on the oxygen and hydrogen diffusion of mixed ionic (oxide ionic or/and protonic)–electronic conducting materials for these devices, and its role in their performance. The main laws of bulk diffusion and surface exchange are highlighted. Isotope exchange techniques allow us to study these processes in detail. Ionic transport properties of conventional and state-of-the-art materials including perovskites, Ruddlesden–Popper phases, fluorites, pyrochlores, composites, etc., are reviewed.
Cite: Sadykov V. , Pikalova E. , Sadovskaya E. , Shlyakhtina A. , Filonova E. , Eremeev N.
Design of Mixed Ionic-Electronic Materials for Permselective Membranes and Solid Oxide Fuel Cells Based on Their Oxygen and Hydrogen Mobility
Membranes. 2023. V.13. N8. 698 :1-53. DOI: 10.3390/membranes13080698 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
Submitted: Jun 27, 2023
Accepted: Jul 25, 2023
Published print: Jul 27, 2023
Published online: Jul 27, 2023
Identifiers:
Web of science: WOS:001057459500001
Scopus: 2-s2.0-85168829894
Elibrary: 54948173
Chemical Abstracts: 2023:1809867
Chemical Abstracts (print): 184:147900
PMID: 37623759
OpenAlex: W4385348403
Citing:
DB Citing
OpenAlex 14
Scopus 14
Web of science 12
Elibrary 8
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