Why non-Heme Mn Complexes of Amino 2-quinolylmethyl Ligands are Inactive in "Oxidation Catalysis? An Insight from X-ray Data | Sciact - CRIS-система Института катализа

Why non-Heme Mn Complexes of Amino 2-quinolylmethyl Ligands are Inactive in "Oxidation Catalysis? An Insight from X-ray Data Краткое сообщение

Журнал

Inorganic Chemistry Communications
ISSN: 1387-7003

Вых. Данные

Год: 2023, Том: 156, Номер статьи : 111282, Страниц : 4 DOI: 10.1016/j.inoche.2023.111282

Ключевые слова

Biomimetic chemistry; C–H activation; Hydroxylation; Manganese; Oxidation

Авторы

Ottenbacher Roman V. ¹ , Medvedev Alexander G. ² , Nefedov Andrey A. ^3,4 , Bryliakov Konstantin P. ⁵

Организации

1	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russia
2	Kurnakov Institute of General and Inorganic Chemistry RAS, Leninsky Pr. 31, Moscow 119991, Russia
3	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Pr. Lavrentieva 9, Novosibirsk 630090, Russia
4	Novosibirsk State University, Pirogova 1, Novosibirsk 630090, Russia
5	Zelinsky Institute of Organic Chemistry RAS, Leninsky Pr. 47, Moscow 119991, Russia

Информация о финансировании (2)

1	Российский научный фонд	20-13-00032 (АААА-А20-120071590003-2)
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	0238-2021-0005 (АААА-А21-121011490018-2)

In the last decade, manganese complexes with bis-amino-bis-pyridylmethyl and structurally related N4 donor ligands have emerged as efficient catalysts of selective epoxidations and C–H oxidations of organic substrates with H2O2. Although a plethora of various ligand structures have been designed, (quinolin-2-yl)methyl moieties have not been involved in constructing such catalysts. Herewith we report crystal structures of several Mn complexes with (quinolin-2-yl)methyl and discuss possible reasons of their inactivity in oxidation catalysis.

Ottenbacher R.V. , Medvedev A.G. , Nefedov A.A. , Bryliakov K.P.
Why non-Heme Mn Complexes of Amino 2-quinolylmethyl Ligands are Inactive in "Oxidation Catalysis? An Insight from X-ray Data
Inorganic Chemistry Communications. 2023. V.156. 111282 :1-4. DOI: 10.1016/j.inoche.2023.111282 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	29 июн. 2023 г.
Принята к публикации:	21 авг. 2023 г.
Опубликована online:	23 авг. 2023 г.
Опубликована в печати:	1 окт. 2023 г.

Web of science:	WOS:001071448200001
Scopus:	2-s2.0-85169014620
РИНЦ:	54948910
Chemical Abstracts:	2023:1789057
OpenAlex:	W4386101202

БД	Цитирований
Scopus	2
OpenAlex	2
Web of science	2
РИНЦ	2