Bioinspired Non‐Heme Mn Catalysts for Regio‐ and Stereoselective Oxyfunctionalizations with H2O2 Обзор
| Журнал |
Chemistry - A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765 |
||||||||
|---|---|---|---|---|---|---|---|---|---|
| Вых. Данные | Год: 2023, Том: 29, Номер: 66, Номер статьи : e202302772, Страниц : 16 DOI: 10.1002/chem.202302772 | ||||||||
| Ключевые слова | Bioinspired catalysis; C‒H activation; Enantioselective oxidation; Manganese; Mechanism | ||||||||
| Авторы |
|
||||||||
| Организации |
|
Информация о финансировании (1)
| 1 | Российский научный фонд | 20-13-00032 (АААА-А20-120071590003-2) |
Реферат:
In recent years, metalloenzymes-mediated highly selective oxidations of organic substrates under mild conditions have been inspiration for developing synthetic bioinspired catalyst systems, capable of conducting such processes in the laboratory (and, in the future, in industry), relying on easy-to-handle and environmentally benign oxidants such as H2O2. To date, non-heme manganese complexes with chiral bis-amino-bis-pyridylmethyl and structurally related ligands are considered as possessing the highest synthetic potential, having demonstrated the ability to mediate a variety of chemo- and stereoselective oxidative transformations, such as epoxidations, C(sp3)‒H hydroxylations and ketonizations, oxidative desymmetrizations, kinetic resolutions, etc. Furthermore, in the past few years non-heme Mn based catalysts have become the major platform for studies focused on getting insight into the molecular mechanisms of oxidant activation and (stereo)selective oxygen transfer, testing non-traditional hydroperoxide oxidants, engineering catalytic sites with enzyme-like substrate recognition-based selectivity, exploration of catalytic regioselectivity trends in the oxidation of biologically active substrates of natural origin. This contribution summarizes the progress in manganese catalyzed C‒H oxygenative transformations of organic substrates, achieved essentially in the past 5 years (late 2018‒2023).
Библиографическая ссылка:
Ottenbacher R.V.
, Bryliakova A.A.
, Kurganskii V.I.
, Prikhodchenko P.V.
, Medvedev A.G.
, Bryliakov K.P.
Bioinspired Non‐Heme Mn Catalysts for Regio‐ and Stereoselective Oxyfunctionalizations with H2O2
Chemistry - A European Journal. 2023. V.29. N66. e202302772 :1-16. DOI: 10.1002/chem.202302772 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Bioinspired Non‐Heme Mn Catalysts for Regio‐ and Stereoselective Oxyfunctionalizations with H2O2
Chemistry - A European Journal. 2023. V.29. N66. e202302772 :1-16. DOI: 10.1002/chem.202302772 WOS Scopus РИНЦ CAPlus PMID OpenAlex
Даты:
| Поступила в редакцию: | 24 авг. 2023 г. |
| Принята к публикации: | 29 авг. 2023 г. |
| Опубликована online: | 29 авг. 2023 г. |
| Опубликована в печати: | 24 нояб. 2023 г. |
Идентификаторы БД:
| Web of science: | WOS:001084914600001 |
| Scopus: | 2-s2.0-85174191155 |
| РИНЦ: | 54967837 |
| Chemical Abstracts: | 2023:2142980 |
| PMID (PubMed): | 37642264 |
| OpenAlex: | W4386251398 |