2,6-Bis(4,5-diethyl-1H-imidazol-2-yl)pyridine and Its Complex with Divalent Iron: The Synthesis and Study | Sciact - CRIS-system of Boreskov Institute of Catalysis

2,6-Bis(4,5-diethyl-1H-imidazol-2-yl)pyridine and Its Complex with Divalent Iron: The Synthesis and Study Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2023, Volume: 72, Number: 9, Pages: 2041-2047 Pages count : 7 DOI: 10.1007/s11172-023-3998-4

Tags

2,6-bis(4,5-diethyl-1H-imidazol-2-yl)pyridine, synthesis, iron(II) complex, IR spectroscopy, EXAFS spectroscopy, magnetic susceptibility, quantum chemical calculations

Authors

Os’kina I.A. ¹ , Korotaev E.V. ² , Trubina S.V. ² , Kriventsov V.V. ³ , Kozlova S.G. ² , Tikhonov A.Ya. ¹ , Lavrenova L.G. ²

Affiliations

1	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrentyeva, 630090 Novosibirsk, Russian Federation
2	A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentyeva, 630090 Novosibirsk, Russian Federation
3	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrentyeva, 630090 Novosibirsk, Russian Federation

Funding (3)

1	Ministry of Science and Higher Education of the Russian Federation	FWUZ-2021-0005 (121031700313-8)
2	Ministry of Science and Higher Education of the Russian Federation	ГЗ-2021-2023
3	Ministry of Science and Higher Education of the Russian Federation	FWUE-2022-0002 (122040400035-3)

Reaction of pyridine-2,6-dicarbaldehyde with hexane-3,4-dione and ammonium acetate affords 2,6-bis(4,5-diethyl-1H-imidazol-2-yl)pyridine (L) which was used as ligand in the synthesis of iron(II) chloride complex [FeL2]Cl2•H2O. Conclusions about the structure of the coordination site of the complex were drawn based on the results of IR spectroscopy, EXAFS spectroscopy, static magnetic susceptibility studies, and quantum chemical calculations.

Os’kina I.A. , Korotaev E.V. , Trubina S.V. , Kriventsov V.V. , Kozlova S.G. , Tikhonov A.Y. , Lavrenova L.G.
2,6-Bis(4,5-diethyl-1H-imidazol-2-yl)pyridine and Its Complex with Divalent Iron: The Synthesis and Study
Russian Chemical Bulletin. 2023. V.72. N9. P.2041-2047. DOI: 10.1007/s11172-023-3998-4 WOS Scopus РИНЦ ANCAN OpenAlex

Оськина И.А. , Коротаев Е.В. , Трубина С.В. , Кривенцов В.В. , Козлова С.Г. , Тихонов А.Я. , Лавренова Л.Г.
Синтез и исследование 2,6-бис(4,5-диэтил-1Н-имидазол-2-ил)пиридина и комплекса железа(II) на его основе
Известия Академии наук. Серия химическая. 2023. Т.72. №9. С.2041-2047. РИНЦ

Submitted:	Feb 16, 2023
Accepted:	May 12, 2023
Published print:	Sep 26, 2023
Published online:	Sep 26, 2023

Web of science:	WOS:001074328300009
Scopus:	2-s2.0-85172273093
Elibrary:	55169863
Chemical Abstracts:	2023:2028359
Chemical Abstracts (print):	184:224740
OpenAlex:	W4387053732

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