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The Manifestation of Surface and Size Effects in the Magnetic Properties of ε-Fe2O3 Nanoparticles. (Brief overview) Full article

Journal Physics of the Solid State
ISSN: 1063-7834 , E-ISSN: 1090-6460
Output data Year: 2023, Volume: 65, Number: 6, Pages: 938-946 Pages count : 9 DOI: 10.21883/pss.2023.06.56105.12h
Tags iron oxide ε-Fe2O3, nanoparticles, size effect, surface magnetic anisotropy
Authors Balaev D.A. 1 , Dubrovsky A.A. 1 , Knyazev Yu.V. 1 , Semenov S.V. 1 , Kirillov V.L. 2 , Martyanov O.N. 2
Affiliations
1 Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
2 Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, Russia

Abstract: Polymorphic modification of iron oxide, known as ε-Fe2O3, exists only in the form of nanoparticles with characteristic sizes up to several tens of nanometers. Particles of these sizes exhibit a large coercive force, about 20 kOe at room temperature. In the temperature range of 80-150 K, a magnetic transition occurs in ε-Fe2O3, accompanied by a sharp decrease in the coercive force. At the same time, there are significant differences in the magnetic behavior of "large" (~20 nm) particles and ultra-small particles (up to 6 nm). A number of experimental facts indicate the manifestation of size effects that lead to a change in the magnetic structure in particles of these sizes. In addition, a surface effect is also manifested for such particles - a significant contribution to the magnetic behavior is governed by surface magnetic anisotropy. In this paper, a brief review of the manifestation of these size and surface effects in the magnetic properties of ε-Fe2O3 nanoparticles is carried out. Keywords: iron oxide ε-Fe2O3, nanoparticles, size effect, surface magnetic anisotropy.
Cite: Balaev D.A. , Dubrovsky A.A. , Knyazev Y.V. , Semenov S.V. , Kirillov V.L. , Martyanov O.N.
The Manifestation of Surface and Size Effects in the Magnetic Properties of ε-Fe2O3 Nanoparticles. (Brief overview)
Physics of the Solid State. 2023. V.65. N6. P.938-946. DOI: 10.21883/pss.2023.06.56105.12h РИНЦ OpenAlex
Original: Балаев Д.А. , Дубровский А.А. , Князев Ю.В. , Семенов С.В. , Кириллов В.Л. , Мартьянов О.Н.
Проявление поверхностных и размерных эффектов в магнитных свойствах наночастиц ε-Fe2O3. (Краткий обзор)
Физика твердого тела. 2023. Т.65. №6. С.979-988. DOI: 10.21883/FTT.2023.06.55654.12H РИНЦ OpenAlex
Dates:
Submitted: Apr 17, 2023
Accepted: May 11, 2023
Identifiers:
Elibrary: 59755372
OpenAlex: W4385653566
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