Zinc(II) and Nickel(II) Complexes with N-[2-(2-diethylphoshponylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide: Synthesis, Structure, and Photoluminescence Properties | Sciact - CRIS-system of Boreskov Institute of Catalysis

Zinc(II) and Nickel(II) Complexes with N-[2-(2-diethylphoshponylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide: Synthesis, Structure, and Photoluminescence Properties Full article

Journal

Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255

Output data

Year: 2023, Volume: 558, Article number : 121765, Pages count : 10 DOI: 10.1016/j.ica.2023.121765

Tags

Azomethines, Zinc and nickel complexes, UV–Vis spectra, Photoluminescence, Synchrotron single-crystal X-ray diffraction

Authors

Burlov Anatolii S. ¹ , Vlasenko Valery G. ² , Popov Leonid D. ³ , Koshchienko Yurii V. ¹ , Garnovskii Dmitrii A. ⁴ , Kolodina Alexandra A. ¹ , Korshunova Evgeniya V. ¹ , Zubavichus Yan V. ⁵ , Lazarenko Vladimir A. ⁶

Affiliations

1	Southern Federal University, Institute of Physical and Organic Chemistry, Stachki ave. 194/2, 344090 Rostov-on-Don, Russian Federation
2	Southern Federal University, Institute of Physics, Stachki ave. 194, 344090 Rostov-on-Don, Russian Federation
3	Southern Federal University, Department of Chemistry, Zorge st. 7, 344090 Rostov-on-Don, Russian Federation
4	Southern Scientific Center of Russian Academy of Sciences, 41 Chekhova str., 344006 Rostov-on-Don, Russian Federation
5	Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Nikolskii pr., 1, 630559 Koltsovo, Russian Federation
6	National Research Center «Kurchatov Institute», Acad. Kurchatov Sq. 1, 123182 Moscow, Russian Federation

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	ГЗ-2021-2023
2	Ministry of Science and Higher Education of the Russian Federation	FENW-2023-0011

Two Zn(II) and Ni(II) complexes derived from the N-[2-(2-diethylphosphonylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide ligand (HL) with stoichiometry ML2 (M = Zn, Ni) have been synthesized. Their structures have been established using elemental analysis, IR, 1H NMR, UV–Vis spectroscopy, and synchrotron single-crystal X-ray diffraction. The Zn(II) and Ni(II) metal sites therein adopt the tetrahedral configuration. The DMSO and toluene solutions of the Zn(II) complex manifest photoluminescence in the blue-violet spectral range characterized by PL maxima at 436 and 432 nm and quantum yields of 0.15 and 0.30, respectively.

Burlov A.S. , Vlasenko V.G. , Popov L.D. , Koshchienko Y.V. , Garnovskii D.A. , Kolodina A.A. , Korshunova E.V. , Zubavichus Y.V. , Lazarenko V.A.
Zinc(II) and Nickel(II) Complexes with N-[2-(2-diethylphoshponylethyliminomethyl)phenyl]-4-methylbenzenesulfonamide: Synthesis, Structure, and Photoluminescence Properties
Inorganica Chimica Acta. 2023. V.558. 121765 :1-10. DOI: 10.1016/j.ica.2023.121765 WOS Scopus РИНЦ AN OpenAlex publication_identifier_short.sciact_skif_identifier_type

Submitted:	Jul 10, 2023
Accepted:	Sep 12, 2023
Published online:	Sep 14, 2023
Published print:	Dec 1, 2023

Web of science:	WOS:001081500400001
Scopus:	2-s2.0-85171474371
Elibrary:	64934359
Chemical Abstracts:	2023:1959042
OpenAlex:	W4386701169
publication_identifier.sciact_skif_identifier_type:	590

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